Earth Materials Flashcards
the substance of which any physical object is composed
matter
States of matter
solid
liquid
gas
controlling factors of matter
temperature and pressure
the make-up of solid matter on Earthj
atoms > elements > compounds > minerals > rocks
fundamental building blocks
elements
what is Goldschmidt’s classification?
a geochemical classification which groups the chemical elements according to their preferred host phases
silicate loving, mainly consists of the highly reactive metals of the s and f-blocks
lithophiles
iron-loving, high-density transition metals that tend to bond with metallic iron in the solid or molten state
siderophile
sulfur-loving, poor metals, and heavier nonmetals that have a low affinity for oxygen and prefer to bond with sulfur as highly insoluble sulfides
chalcophile
gas loving, h, c, n noble gases, are defined as those that are found chiefly or exclusively in the form of gases
atmophile
have in common increasing unpaired electrons
LREE - Light Rare Earth Materials
have paired electrons (a clockwise and counter-clockwise spinning electron)
HREE - Heavy Rare Earth Materials
builds elements, smallest particle that uniquely defines an element
atoms
Protons + neutrons define the ___ of an atom
nucleus
Layers of electrons that orbit around the nucleus
are called____
orbitals or energy-level shells
atoms of the same element that have different mass numbers
isotopes
protons + average # neutron
atomic weight
= # protons + # neutrons
mass number
an atom that has gained or lost an electron`
ion
a loss of electrons, resulting in a positive (+) charge
cation
a gain of electrons, resulting in a negative (-) charge
anion
consists of elements that combine in a specific ratio
chemical compount
smallest quantity of a compound is called a __
Molecule
molecules are held together by __.
- formation of a compound by combining two or more elements
- manner in which electrons are distributed among
atoms
chemical bonding
In bonded atoms, electrons may be___,
_____, or _____.
lost, gained, hared
types of chemical bonding and describe
Ionic bonding: electrons are transferred between atoms forming attracting ions/ orderly arrangement of oppositely charged ions. bonds are moderately strong
Covalent bonding: electrons are shared between atoms, generally strong bonds
Metallic Bonding: electrons drift around from atom to atom, good conductors of electrical current, weaker, less common
Van der Waals bonding:
* sheets of covalently bonded atoms held together by
weak electrostatic forces
* very weak bond
Where electronegativity differences in transitional ionic–covalent bonds are smaller than 1.68, the bonds are primarily electron-_____ bonds.
sharing covalent
Where electronegativity differences are larger than 1.68, the bonds are primarily electron-___ bonds
transfer ionic
{1-exp[(-0.25)(E1-E2)2]} x 100
%IC (ionic character)
Calculate NaCl’s %ionic character.
Given:
Electronegativity of Na= 0.93
Electronegativity of Cl= 3.16
–
makes up solid matter on Earth
minerals
Definition of Minerals
naturally occurring
inorganic
definite chemical composition
ordered crystalline structure
homogenous solid
definition of a rock
a solid aggregate of minerals
diagnostic property/description of alabaster
massive
diagnostic property/description of selenite
bladed
diagnostic property/description of satin spar
fibrous
diagnostic property/description of enargite and luzonite
arsenosulfides
diagnostic property/description of Semi-Anthracite
form of coal
diagnostic property/description of dolimite
cast for fossils
diagnostic property/description of garnierite
nickel ore
diagnostic property/description of bornite
peacock ore, can be scratch by 5-cent copper
diagnostic property/description of copper concentrate
Cu, Fe, Mg , Au in powdered form for smelting into coppper wire
diagnostic property/description of granite
quartz, hornblende, k-felds
diagnostic property/description of olivine group: Forsterite (Fe) and Fayalite (Mg)
mantle consituents
diagnostic property/description of pyroxenes
90-deg cleav
diagnostic property/description of amphiboles
60-120 cleav
diagnostic property/description of micas
bird’s eye extinction
Abundance of Oxygen in the crust
46.6%
Abundance of Silicon in the crust
27.7%
Abundance of Al in the crust
8.1%
Abundance of Fe in the crust
5%
Abundance of Ca in the crust
3.6%
Abundance of Na in the crust
2.8%
Abundance of K in the crust
2.6%
Abundance of Mg in the crust
2.1%
independent tetrahedron satisfied in charge and held together by cation
Nesosilicate - Si:O ratio – 1:4
single – 2 adjacent silica tetrahedral linked through shared oxygen ions
Inosilicate - 1:3
double – tetrahedral share 2, then 3 corner oxygens alternately
Inosilicate - 4:11
each tetrahedron shares a corner oxygen with 3 neighbors
Phyllosilicate - 2:5
continuous 3-dimensional network of tetrahedral sharing all 4 corners
Tectosilicate 1:2
tetrahedral pair by sharing one corner. No important rock-forming minerals
Sorosilicate 2:7
tetrahedral each share two corners to form rings
Cyclosilicate 1:3
Polymorphs vs. Isomorphs vs. Pseudomorphs
Polymorphs are minerals with the same chemical
composition but different crystal structures. The
conditions are such things as temperature (T) and
pressure (P)
Pseudomorphs Minerals taking crystal form of another, pre-existing mineral. Original crystal should be: Euhedral/Subhedral at the time of formation
The same structure but with different chemical
composition.
Polymorphs of AL2SiO5 - Kyanite
andulsite
sillimanite
Polymorphs of Carbon
Diamond
Graphite
polymorph of Sphalerite
wurtzite
polymorph of Pyrite
Marcasite
Polymorph of SiO2 - Quartz
Stishovite
Coesite
a-quartz
b quartz
cristobalite
tridymite
processes of pseudomorphs
Replacement- pre-existing atoms are replaced by
new mineral retaining its external crystal form
Pyrite can be replaced by Geothite
Fluorite by quartz
Loss of Constituent from original crystals
dissolution of carbonate form
azurite to produce native copper
Encrustation – the new mineral mimics the original mineral’s crystal form.
example of isomorph
continuous series of bowens reaction
Ionic substitution (also called solid solution) occurs
because some elements (ions) have the _____ and thus substitution for one another
in a crystal structure is possible.
same size and charge,