E2 Reactions Flashcards

1
Q

Electrons from the C-H sigma bond are _________ atrracted into the vacant sigma antibinding orbital associated with the ajacent C-X

A

Hyperconjugatively

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

What is the pKa of Nucleophile (base) in E2 mechanism?

A

> 10

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

What is the driving force of E2

A

Large decrease in basicity

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

What is the rate law for E2

A

Rate=k[base][alkyl halide]

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

SN2 is favoured if…

A
  1. The reactants are sterically free

2. The nucleophile is too basic

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

E2 is favoured if…

A
  1. The reactants are sterically hindered

2. The nucleophile is very basic

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Is OH- a good nucleophile in ethanol

A

No because of hydrogen bonding interaction trapping OH-. But its a strong base

How well did you know this?
1
Not at all
2
3
4
5
Perfectly