Dynamic Surface L4 Flashcards
How are non-clastic limestones produced?
By biogeochemical processes or direct precipitation
Where are limestones generally produced?
The basin where they are deposited
What is the reversible carbonate reaction?
CaCO3 + H2O + CO2 <–> Ca2+ + 2HCO3-
What is the name of the forward reaction in the reversible carbonate reaction?
Dissolution
What is the name of the backwards reaction in the reversible carbonate reaction?
Precipitation
In what conditions is the dissolution of carbonate favoured?
Low temperature
High hydrostatic pressure
In what conditions is the precipitation of carbonate favoured?
High temperature
Low hydrostatic pressure
Why does the rate of dissolution of carbonates increase at lower temperatures?
Warm water is more susceptible to evaporation
What is the main control on the reversible carbonate reaction?
The addition and removal of CO2
How does removing CO2 affect the reversible carbonate reaction?
Precipitation is favoured
How does adding CO2 affect the reversible carbonate reaction?
Dissolution is favoured
What are the 2 common polymorphs of CaCO3?
Calcite
Aragonite
What crystal system does calcite display?
Hexagonal
What crystal system does aragonite display?
Orthorhombic
What happens to aragonite when taken out of warm marine conditions?
It will transform into calcite
What concentration of magnesium does aragonite contain in ppm?
Less than 500ppm
Up to what concentration of Sr can aragonite contain in ppm?
Up to 10,000ppm of Sr substituting for Ca
What are the 4 components of limestones?
Skeletal grains
Non-skeletal grains
Micrite
Cements
What is an allochem?
A carbonate particle that was formed outside of the depositional environment and transported in
What is an orthochem?
Carbonate sediments that form within the depositional environment that represent the rock cement or matrix.
What are skeletal and non-skeletal grains known as in carbonate rocks?
Allochems
What is micrite?
A very fine grained component that often makes up the matrix of limestone