dyes Flashcards
cellulose fibres
amine groups (-NH2) enable dye molecules to form hydrogen bonds with cellulose fibres (cotton, rayon, linen) because these fibres contain lots of OH groups
wool, silk and nylon
acidic groups like carboxylic acid or sulfonic acid (-SO3H) help dyes to bind to alkaline -NH- links
H+ ions move from dye to fibre molecule, and ionic interactions then hold them together
ionic salt groups
-SO3NA
allow the dyes to bind with -NH- links
the salt groups dissociate when you dissolve the dye in water to give -SO3 - groups
to make the NH2+ groups, you need to add acid to provide H+ ions to the -NH- links. The SO3- groups will then bind to the -NH2+- links
fibre reactive dyes
most permanent type of dye
have a functional group that will react with the OH of NH group in the fibre, forming strong covalent bonds
chromophores
the structures in molecules that give them their colour
what molecular features do chromophores contain?
double or triple bonds, lone pairs of electrons, benzene rings
usually form part of a delocalised electron system
what functional group makes a dye more soluble?
SO3- Na+ (sulfate ion usually in the form of its sodium salt)