don't cry don't cry don't cry don't cry Flashcards
CATAYLST
this is a substance which alters the speed of a reactionn by providing an alternative route of lower EA. It remains chemically unchanged and unchanged in mass at the end of the reaction
haber process production NH3
finely divided FE catalyst
hydrogenation of alkenes
finely divided Ni catalyst
contact process- manufacturing H2SO4
V205 (vanadium 5 oxide)
oxidation of NH3
Pt and Rd gauze
Explaining catalyst thingy
the gases form WEAK BONDS with the metal atom- this is called ADSORPTION. This holds the gases in just the right position to react. Collision FREQ and GEOMETRY increases. The bonds in the reactant molecules are WEAKENED. (Ea is lowered)
Products break away- DESORPTION. This frees up room on the surface of the catalyst for more gases to take place and react
cisplatin
anticancer drug. Cisplatin forms coordinate bonds to a basic site in the DNA of cancer cells. This process prevents cancerous DNA from replicating, effectively killing the cancerous cells. Toxic.
edta
used in blood transfusion and surgery to remove CA IONS which cause blood clotting. Edta for complex with ca required for clotting action.
Sequesting agent.
Cr +3
amphoteric, react with a base
D block
This is an element which has an atom with its highest energy electron in s sun shell
Transition element
Forms atleast one stable ion with a partially filled d sub shell
Ox states above +3
Electrons may be regarded as partially lost to a more electronegative atom in a covalent bond
Complex ion
Formed by the co ordination of lone pair of electrons from a donor (called a ligand ) to an atom or ion (acceptor) which has empty orbitals to accommodate
Ligand
Ion or molecule that is capable of donating one or more line pair of electrons via a co ordinate bond to a central metal atom or ion in a complex
Bidentate
A bidentate ligand USES two lone pair of electrons to form two coordinate bonds with central metal atom or ion in a complex
Ethanedioate ion
1,2-diaminoethane
Explain colour
No d electrons or full d orbits it will be colourless as bond-d transitions
Ligand strength alkyl
Alkyl groups are electron donating so ally groups in amines push electrons towards N atom and will destabilise the lone pair of electrons making it more likely to be donated to central metal atom or ion