don't cry don't cry don't cry don't cry Flashcards

1
Q

CATAYLST

A

this is a substance which alters the speed of a reactionn by providing an alternative route of lower EA. It remains chemically unchanged and unchanged in mass at the end of the reaction

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2
Q

haber process production NH3

A

finely divided FE catalyst

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3
Q

hydrogenation of alkenes

A

finely divided Ni catalyst

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4
Q

contact process- manufacturing H2SO4

A

V205 (vanadium 5 oxide)

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5
Q

oxidation of NH3

A

Pt and Rd gauze

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6
Q

Explaining catalyst thingy

A

the gases form WEAK BONDS with the metal atom- this is called ADSORPTION. This holds the gases in just the right position to react. Collision FREQ and GEOMETRY increases. The bonds in the reactant molecules are WEAKENED. (Ea is lowered)
Products break away- DESORPTION. This frees up room on the surface of the catalyst for more gases to take place and react

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7
Q

cisplatin

A

anticancer drug. Cisplatin forms coordinate bonds to a basic site in the DNA of cancer cells. This process prevents cancerous DNA from replicating, effectively killing the cancerous cells. Toxic.

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8
Q

edta

A

used in blood transfusion and surgery to remove CA IONS which cause blood clotting. Edta for complex with ca required for clotting action.
Sequesting agent.

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9
Q

Cr +3

A

amphoteric, react with a base

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10
Q

D block

A

This is an element which has an atom with its highest energy electron in s sun shell

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11
Q

Transition element

A

Forms atleast one stable ion with a partially filled d sub shell

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12
Q

Ox states above +3

A

Electrons may be regarded as partially lost to a more electronegative atom in a covalent bond

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13
Q

Complex ion

A

Formed by the co ordination of lone pair of electrons from a donor (called a ligand ) to an atom or ion (acceptor) which has empty orbitals to accommodate

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14
Q

Ligand

A

Ion or molecule that is capable of donating one or more line pair of electrons via a co ordinate bond to a central metal atom or ion in a complex

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15
Q

Bidentate

A

A bidentate ligand USES two lone pair of electrons to form two coordinate bonds with central metal atom or ion in a complex

Ethanedioate ion
1,2-diaminoethane

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16
Q

Explain colour

A

No d electrons or full d orbits it will be colourless as bond-d transitions

17
Q

Ligand strength alkyl

A

Alkyl groups are electron donating so ally groups in amines push electrons towards N atom and will destabilise the lone pair of electrons making it more likely to be donated to central metal atom or ion