DML1: Bonding to dentine Flashcards

1
Q

Why are adhesives used in dentistry

A

Because the tooth tissue is hydrophilic and restorative materials are hydrophobic; thus adhesives allow chemical bonding to occur which is key for the longevity of the restoration

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2
Q

What are the advantages of using adhesives

A
  • better aesthetics
  • tooth tissue conservation
  • reinforces weak tooth structure
  • reduced marginal leakage
  • reduced potential for pulp sensitivity
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3
Q

What are the ideal requirements for adhesives

A
  1. Provide high bond strength to enamel/dentine
  2. Immediate and durable bond formation
  3. Prevent ingress of bacteria (typically at margins)
  4. Safe and simple usage
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4
Q

What type of adhesive is used for bonding resin to enamel

A

Acid-etch technique which is used in the placement of anterior and posterior composites, compomers, resin-bonded bridges, veneers and orthodontic appliances

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5
Q

What issues arise when bonding adhesive to enamel

A
  • surface tension of enamel is lower than adhesive resin
  • this means perfect wetting cannot take place
  • enamel is covered by a pellicle layer which has an even lower surface energy which will also prevent perfect wetting
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6
Q

How are the issues arising when bonding adhesive resin to enamel resolved

A
  • Raise the surface energy of enamel by removing pellicle layer through etching
  • This roughens the surface
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7
Q

How is the pellicle layer removed when the enamel is etched

A

By the use of 30-50% Phosphoric acid (acid primer) and there is an acid bade reaction where the acid dissolves enamel surface hydroxyapatite giving a frosty appearance

Therefore there is micromechanical retention between the enamel and the resin because there is an increased SA for adhesive influx

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8
Q

What are the main effects of the acid-etch technique

A

Removal of the pellicle layer and contaminants with acid results in

  • increased surface roughness of enamel
  • bonding area is increased
  • surface energy is raised
  • improved wettability for resin to run into enamel rods
  • opens inner prism area for interlocking tag formation
  • increased area of contact and micromechanical bonding
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9
Q

What is the problem with over etching

A

It can break down enamel prisms needed for tag formation and this compromises the bonding

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10
Q

How is the resin applied after acid-etching the enamel

A
  • low viscosity resin (unfilled Bis-GMA or dentine adhesive resin) is used prior to composite
  • this is applied to the dry etched surface
  • it will form resin tags which penetrate 30um deep
  • a filled resin is applied on top of this unfilled resin
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11
Q

Why does a restorative resin material have to be adhesively bonded to dentine

A

To retain the restoration in the cavity and to eliminate marginal/internal gaps in order to prevent bacterial microleakage

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12
Q

Why is a bonding agent used to bind a restorative resin to dentine

A

Because dentine is even more hydrophilic than enamel and this bonding agent will provide added strength to the restored tooth by sealing the dentinal tubules
- this prevents dentine hypersensitivity

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13
Q

Why is it important that the dentinal tubules are sealed

A

Because they communicate with the pulp and are permeable to drugs and chemicals which can injure the pulp

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14
Q

What happens to the dentine structure when it is cut

A
  1. Fluid is pumped through dentinal tubules giving a wet surface
  2. Inorganic hydroxyapatite crystals are broken up, the collagen is stretched, torn and smeared over the cut surface forming smear plugs
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15
Q

What is the smear layer which covers cut dentine

A

A layer of denatured collagen and debris which is weakly bound to the dentine ; it is contaminated with bacteria (carious) and cutting debris

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16
Q

Why is it important that the adhesive resin acts as an effective seal for the dentinal tubules

A

Because when the smear layer is removed the dentine tubules are open and so exposed to bacteria and irritants - this has to be removed because it is a wet layer which makes bonding of the resin difficult

17
Q

What are the three components of dentine bonding agents

A
  1. Conditioner (modifies/clears smear layer)
  2. Coupling agent/primer (bonding adhesive)
  3. Sealer (seals the dentinal tubules)

Order = Etch-prime-bond

18
Q

What is a dentine conditioner

A

Component of the dentine bonding agent which is an acid solution and so removes/modifies the smear layer

It has to then be rinsed with water to leave the demineralised dentine surface and exposed tubules

19
Q

What is the coupling agent/primer and what does it consist of

A

This acts as an adhesive in the dentine bonding agent and bings the hydrophilic dentine to hydrophobic resin

It consists of

  1. Bi-functional HEMA molecule that is dissolved in a solvent
  2. Spacer molecule which provides flexibility to the coupling agent
  3. Ethanol/acetone solvent (water chasers) this displaces water form tubules so the OH groups can saturate them via a molecular entanglement network
20
Q

What is a dentine sealer and what does it do

A

It is the third component of the dentine bonding agent which contains unfilled Bis-GMA/UDMA and adhesion promoters to dentine

  • it makes the dentine surface more hydrophobic
  • it is light cured
21
Q

What is the hybrid zone

A

The interpenetrating layer of dentine and resin

22
Q

What issues arise with excessive desiccation of dentine

A

Post operative pulpal sensitivity and a poor bond

  • pulpal inflammation will occur if there is bond failure leading to bacterial leakage
  • there could be delayed allergic reaction or contact dermatitis with HEMA
23
Q

What are the causes of breakdown in the adhesive bond

A
  1. Polymerisation shrinkage
  2. Differential thermal expansion and contraction
  3. Internal stresses from occlusal loading
  4. Chemical attack (hydrolysis)
24
Q

What does the breakdown in the adhesive bond result in

A
  • unsightly marginal staining
  • pulpal sensitivity
  • the restoration may be lost
25
Q

When is the all in one adhesive used

A

In paediatric dentistry