Determination of Density, Specific Gravity, Viscosity of Liquid Fuels Flashcards
is a combustible or energy generating molecules that can produce
Kinetic Energy and contrasted with Solid fuels and Gaseous fuels.
LIQUID FUEL
Types of liquid fuels
Gasoline, Diesel, Kerosene, Compressed natural gas, Liquefied petroleum gas
(LPG).
is most
suitable method for determining the density or relative density (specific gravity) of
mobile transparent liquids. It can be also be used by viscous oils by allowing sufficient
time for the hydrometer to reach equilibrium or for opaque oils by employing a suitable
meniscus correction.
Hydrometer method
is an instrument used to
measure the viscosity of a fluid.
viscometer
is used For liquids with viscosities which vary with flow
conditions,
Rheometer
Viscometers only measure under one flow
condition Density determination by ____ is a precise method.
Pycnometer
is a piece of laboratory equipment used to measure
the volume of a liquid,the inside diameter of the cylinder shall be at least 25mm greater
than the outside diameter of the hydrometer and the height shall be such that the
appropriate hydrometer floats in the test portion with at least 25mm clearance between
the bottom if the hydrometer and the bottom of the cylinder.
Graduated cylinder(500mL):
is a flask with a stopper
that has a capillary tube through it, which allows air bubbles to escape. The pycnometer
is used to obtain accurate measurements of density.
Pycnometer(50mL)
is an instrument used to measure the
specific gravity (or relative density) of liquids; that is, the ratio of the density of the liquid
to the density of water.
Hydrometer
Used for determining the weight or mass of a sample.
Scientific Balance
are those combustible or energy generating molecules that can be harnessed to create
mechenical energy, usually producing kinetic energy.
Liquid fuels
PROPERTIES OF LIQUID FUELS
Density, Viscosity, Flash point, Pour point, Specific gravity, Sulphur content, Carbon residue
Ratio of the fuel’s mass to its volume at 15 oC, • kg/m3
Useful for determining fuel quantity and quality
Density
Measure of fuel’s internal resistance to flow
Most important characteristic for storage and use
Decreases as temperature increases
Viscosity
Lowest temperature at which a fuel can be heated so that the vapour gives off
flashes when an open flame is passes over it
Flash point of furnace oil: 66oC
Flash point
Lowest temperature at which fuel will flow
Indication of temperature at which fuel can be pumped Calorific value
Heat or energy produced
Gross calorific value (GCV): vapour is fully condensed
Net calorific value (NCV): water is not fully condensed
Pour point
Ratio of weight of oil volume to weight of same water volume at a given
temperature • Specific gravity of water is 1
Hydrometer used to measure
Specific gravity
Depends on source of crude oil and less on the refining process
Furnace oil: 2-4 % sulphur
Sulphuric acid causes corrosion Ash content
Inorganic material in fuel
Typically 0.03 - 0.07%
Corrosion of burner tips and damage to materials /equipments at high
temperatures
Sulphur content
Tendency of oil to deposit a carbonaceous solid residue on a hot surface
Residual oil: >1% carbon residue Water content
Normally low in furnace oil supplied
Carbon residue
The single largest source of liquid fuel is petroleum.
Petroleum (petra=rock;olium=oil) is also known as rock oil or mineral oil.
Crude oil (petroleum) is a viscous liquid containing hydrocarbons , petroleum
also contains small amounts of non-hydrocarbons mineral impurities that we
extract from underground deposits at a depth of 500-1500 ft at various places.
It is mainly composed of various hydrocarbons (like straight chain paraffins,
cycloparaffins or napthenes, olefins, and aromatics) together with small amount
of organic compounds containing oxygen nitrogen and sulphur
PETROLEUM
Carbon: 83-87% Hydrogen: 11-14% Nitrogen: 0-0.5% Sulfur: 0-6% Oxygen: 0-3.5% Plus oxygenated compounds like phenols, fatty acids, ketones and metallic elements like vanadium and nickel.
COMPOSITION OF TYPICAL CRUDE OIL
This type of petroleum is mainly
composed of the saturated hydrocarbons from CH4 to C35H72 and a little of the
napthenes and aromatics. The hydrocarbons from C18H38 to C35H72 are
sometimes called Waxes.
Paraffinic Base Type Crude Petroleum
It contains mainly cycloparaffins or
napthenes with smaller amount of parffins and aromatic hydrocarbons.
Asphalitc Base Type Crude Petroleum
Mixed Base Type Crude Petroleum
It contains both paraffinic and asphaltic
hydrocarbons and are generally rich in semi-solid waxes.
contain a solid combustible mixture of hydrocarbons called kerogen.
Oil shales