Determination of Cu by Titration Flashcards
Subtitle
Complexometric titration
What is complexometric titration?
When one or more strongly bonding lewis bases are attached to the copper cation forming a copper complex
What is the titrant?
The complexing reagent, H4EDTA
What actually complexes to the metal?
EDTA^4-
What color indicator do we use?
Murexide
If the ligand can form more than one coordinate covalent bond (likeEDTA) its called a
chelate, EDTA forms 6
Murexide is added to the blue CU^2+ solution to produce purple, to get it clear you must…?
Add the exact amount of EDTA to bind all of the metals
The changes in color will be
purple - yellow - violet
Why do we add NH4Cl and NH4OH?
to buffer the solution
Ppm is equal to:
mg/liter
Whats the coordination number of copper and EDTA?
6
What is the oxidation number of the copper in complex?
+2
EDTA^4- is best described as a _______ ligand.
hexadentate