Determination of Cu by Titration Flashcards

1
Q

Subtitle

A

Complexometric titration

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2
Q

What is complexometric titration?

A

When one or more strongly bonding lewis bases are attached to the copper cation forming a copper complex

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3
Q

What is the titrant?

A

The complexing reagent, H4EDTA

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4
Q

What actually complexes to the metal?

A

EDTA^4-

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5
Q

What color indicator do we use?

A

Murexide

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6
Q

If the ligand can form more than one coordinate covalent bond (likeEDTA) its called a

A

chelate, EDTA forms 6

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7
Q

Murexide is added to the blue CU^2+ solution to produce purple, to get it clear you must…?

A

Add the exact amount of EDTA to bind all of the metals

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8
Q

The changes in color will be

A

purple - yellow - violet

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9
Q

Why do we add NH4Cl and NH4OH?

A

to buffer the solution

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10
Q

Ppm is equal to:

A

mg/liter

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11
Q

Whats the coordination number of copper and EDTA?

A

6

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12
Q

What is the oxidation number of the copper in complex?

A

+2

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13
Q

EDTA^4- is best described as a _______ ligand.

A

hexadentate

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