Dentine Flashcards
What is the composition of dentine?
70% hydroxyapatite
20% organic material, mainly collagen
10% water
Tubules around 1-5μm width
Why resin bond to dentine?
- Eliminate marginal and internal gaps
- Seal dentinal tubules
- Enhance retention
- Enhance strength
What are the problems of bonding to dentine?
- Formation of a smear layer
- Complex substrate (dentine)
- Hydrophobic resins, hydrophilic dentine
- Fluid flow into tubules
How can we fix the smear layer?
- use of dentine conditioner, usually 37% phosphoric acid but not always. This creates a demineralised surface layer approx 4um thick
How can we bond hydrophobic resins to hydrophilic dentine?
with the use of Hydroxyl groups -OH Carboxyl groups -COOH phosphate groups -P-(OH)3 - these bond with the amino groups in the collagen and the hydroxyl groupss in hydroxyapatite
- bond to hydrophobic resins with methacrylate groups?
- use a space to stick them together, long enough to prevent rigidity and allow both ends to bond freely
- bifunctional monomer = polar group, spacer, methacrylate group
What are dentine primers made of?
A bifunctional monomer:
A polar group
A spacer
A methacrylate group
-A solvent or water to carry the monomer deep into the demineralised collagen
How to prevent fluid flow in tubules?
We now have a surface of hydrophobic methacrylate groups
Bond directly using methacrylate based resin
What is dentine sealer?
Methacrylate based
- Bis-GMA (Bis-GMA bisphenol A-glycidyl methacrylate)
- UDMA (urethane dimethacrylate)
Either light cured or chemically cured
Can contain some bifunctional monomer to aid bonding with the primer
What are the 3 stages to dentine bonding?
- Apply conditioner (removes smear layer and opens tubules)
- Apply primer - bonds to hydrophilic collagen and hydroxyapatite
- Apply sealer - seals tubules and bonds to the primer
What are the concerns with dentine bonding?
Eliminate the marginal gap (due to polymerisation shrinkage)
wet dentine bonding
What happens if you thoroughly dry dentine?
collagen collapses
volatile solvent in primer chases water out of collagen and brings in the bifunctional monomer
What are the 4 types of dentine bonding agents?
Type 1 - etch, prime, seal
Type 2 - etch, prime and seal
Type 3 - etch and prime, seal
type 4 - etch and prime and seal
What is the prime and bond NT?
- Uses acetone to carry primer and sealer into dentine
- Acetone chases water out of the dentine
- Needs time and possibly air to evaporate the acetone
Give an example of a prime and bond NT
- scotchbond 1 XT
- water and ethanol carry primer and sealer
- needs agitation to ensure primer and sealer get into the dentine
What do self etching primers do? (type 3)
Acidic monomers that etch and prime
The smear layer is dissolved, but not removed, collagen demineralised and infiltrates the collagen network
What are the benefits of self etching primers?
- no need to rinse or dry (more consistent results)
- can prevent marginal staining (caused by weak etching of enamel) by pre-etching enamel with phosphoric acid
Which type of bonding agent has the weakest bonds?
Type 4 - all in one
How do all in one systems work?
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