Dental Materials Flashcards
what are the types of amalgam?
conventional
high copper
what is the composition of conventional amalgam?
65% silver 29% tin 6% copper 2% zinc 3% magnesium
what is the composition of high copper amalgam?
40% silver 32% tin 30% copper 2% zinc 3% magnesium
what are the types of alloy morphology that amalgam can come in?
lathe cut
spherical
what is the action of the silver tin compound in the amalgam?
undergoes setting reaction
what is the action of the copper in the amalgam?
strengthens
what is the action of the zinc in the amalgam?
scavenger for oxygen
when does amalgam reach its final strength?
24 hours
what is creep?
amalgam flows manifesting as protrusions at the restoration margins
= produces fractures and ditching
what causes creep?
gamma 2 phase
corrosion of the alloy causes mercury to escape into the crevice = causing expansion
what benefits do corrosion products give?
marginal seal
what removes mercury from the amalgam?
packing and condensation
what are the benefits of bonded amalgam?
reduced prep needed
reduced marginal leakage and post op sensitivity
reinforced tooth structure
what is the composition of the resin matrix in composite?
methacrylate/dimethacrylate monomers - BISGMA
comonomers - TEGMA
what is the action of the TEGMA?
controls viscosity
what is the action of the C to C double bond in composite?
allows free radical polymerisation
what are siloranes?
contain oxiranes = ring opening polymerisation
what is cationic curing?
camphorquinone causes ring opening polymerisation
what is the filler in composite?
quartz, silica, glasses - aluminasilicate, boro silicate, barium oxide
what is the coupling agent in composite?
gamma silane
in what ways can composite be activated?
chemical
light - camphorquinone
what does camphorquinone do?
yields necessary free radicals to start polymerisation
generated by quartz halogen lights `
what is the job of the coupling agent?
transfers stess generated under occlusal loading from rigid brittle filler to ductile polymer matrix
what is the job of the filler?
shock absorber
what are the 4 types of composite?
conventional
microfilled
hybrid
nanocomposites
what is the difference in flowable composite compared to conventional?
less filler
what is GI?
ion leachable glass and polycarboxylic acid
what is the composition of the powder to liquid GI?
p - sodium aluminasilicate glass + 20% CaF
l - aqueous solution of acrylic acid copolymer and tartaric acid to control the set
what is the set reaction of powder and liquid GI?
acid base reaction
what is the set reaction of powder and water GI?
p - sodium aluminasilicate glass + 20% CaF, vacuum dried polyacid