Definitions Flashcards

1
Q

Isotope

A

Atoms of the same element with different numbers of neutrons and therefore different masses

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2
Q

Relative isotopic mass

A

the mass of an atom of an isotope compared with 1/12th of the mass of an atom of carbon-12

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3
Q

Relative atomic mass

A

the wieghted mean mass of an atom of an element compared with 1/12th of the mass of an atom of carbon-12

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4
Q

Relative molecular mass

A

the weighted mean mass of a molecule compared with 1/12th of the mass of carbon-12

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5
Q

Relative formula mass

A

the weighted mean mass of a formula unit compared with 1/12th of the mass of carbon-12

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6
Q

1st ionisation energy

A

The amount of energy required to remove one electron from each atom in one mole of gaseous atoms to form one mole of gaseous 1+ ions

  • Nuclear charge
  • shielding
  • atomic radius
  • nuclear attraction
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7
Q

Oxidation

A

the loss of electrons ((formation of +ions))

an increase in the oxidation number (becomes more positive)

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8
Q

Reduction

A

the gain of electrons ((formations of -ions))

a decrease in oxidation number (becomes less positive)

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9
Q

Oxidising agent

A

a reagent that oxidises (takes electrons from) another species

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10
Q

Reducing agent

A

a reagent that reduces (gives electrons to) another speicies

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11
Q

Acid

A

an acid releases H+ ions in aqueous solution

an acid is a proton donor

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12
Q

weak acid / strong acid

A

A strong acid is fully dissociated in solution and a weak acid partially partially dissociated

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13
Q

Base

A

A proton acceptor

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14
Q

Alkali

A

A soluble base that releases OH- ions in water (/solution)

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15
Q

Salts

A

Salts are ionic compounds formed when the H+ ions in an acid are replaced by metal or ammonium ions

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16
Q

ionic bonding

A

electrostatic attraction between positive and negative ions

17
Q

covalent bonding

A

The stong electrostatic attractions between a shared pair of electrons and the nuclei of bonded atoms

18
Q

lone pair

A

a pair of electrons in the outer shell not used in the bonding

19
Q

dative covalent bond

A

A shared pair of electrons in which the bonded pair is provided by one of the bonded atoms only

20
Q

Average bond enthalpy

A

The average enthalpy that takes place when breaking by homolytic fission one mole of a given type of bond in molecules of a gaseous species

21
Q

metallic bonding

A

The electrostatic attraction between positive metal ions and delocalised electrons

22
Q

malleable

A

can easily be bent into different shapes

23
Q

ductile

A

can be drawn into a wire

24
Q

gaint ionic lattice

A

there is a continuous lattice arrangement of + and - ions in three dimensions

25
VSEPR
Valence shell electron pair repulsion - electron pairs repel each other - the repulsion between lone pair-lone pair>lone pair-bonded pair>bonded pair-bonded pair
26
Van der Waals
London forces and permanent dipole-dipole forces
27
London forces
The London dispersion force is the weakest intermolecular force. The London dispersion force is a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles. This force is sometimes called an induced dipole-induced dipole attraction.
28
electronegativity
The ability of an atom to attract the bonding electrons in a covalent bond
29
Pauling value
defines the electronegativity of an element.
30
permanent dipole
a small charge difference that does not change across a bond with partial charges on the bonding atoms (the result of the bonded atoms having different electronegativities)
31
Polar covalent bond
A bond with a permanent dipole, with positive and negative partial charges on bonded atoms
32
Polar molecule
a molecule with an overall dipole hving taken into account any dipoles across bonds and the shape of the molecule and its structure
33
Hydrogen bond
a hydrogen bond is a strong dipole-dipole attraction between an electron difficient -NH, OH, HF on one molecule and a lone pair of electrons on a highly electronegative atom (N,O,F) on a different atom
34
Group (on periodic table)
A vertical column in the periodic table. Elements in a group have similar chemical properties and their atoms have the same number of outer shell electrons.
35
Period (on periodic table)
Horizontal rows in periodic table. Elements show trends in properties across the period
36
Subshell
A subshell is a group of the same type of orbital
37
Orbitals
Orbitals are regions of an atom containing up to two electrons with opposite spin