Definitions Flashcards

1
Q

Molecular formula

A

A formula which shows the actual number of atoms of each element in a molecule

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2
Q

Molar gas volume

A

The volume of one mole of gas under specified conditions of temperature and pressure e.g 24dm3 at 20C and one atmosphere pressure

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3
Q

Homologous series

A

Compounds which have the same general formula, similar chemical properties and successive members differ by CH2

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4
Q

Functional group

A

The part of a structure which determines the characteristic reactions of the compound

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5
Q

Structural isomers

A

Molecules which have the same molecular formula but different structural formula

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6
Q

Stereoisomers (geometric)

A

Have the same structural formula but different 3D spatial arrangements (are non-superimposable)

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7
Q

Empirical Formula

A

A formula which shows the simplest number ratio of atoms of each element compound

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8
Q

Saturated hydrocarbon

A

Contains no c=c or ctriplec bond

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9
Q

Hydrocarbon

A

Contains hydrogen and carbon only

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10
Q

Thermal cracking

A

Breaking down large molecules into smaller molecules using heat

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11
Q

Subsitution

A

Replacing one atom or group with a different atom or group

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12
Q

Homolytic fission

A

Bond breaking in with one of the shared electrons goes to each atom

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13
Q

Free radical

A

A particle with an unpaired electron

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14
Q

Catalyst

A

A substance which alters the speed of a chemical reaction but does not get used up

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15
Q

Unsaturated hydrocarbon

A

Contains at least one c=c or ctriplec bond

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16
Q

Sigma bond

A

A covalent bond formed by the linear overlap of atomic orbitals resulting in free rotation along bond axis

17
Q

Pi bond

A

A covalent bond formed by the sideways overlap of p orbitals resulting in it being restricted along the bond axis

18
Q

Bond length

A

The distance between the nuclei of two covalently bonded atoms

19
Q

Hydrogenation

A

Addition of hydrogen across a c=c

20
Q

Electrophile

A

An ion or molecule that attacks regions of high electron density

21
Q

Heterolytic fission

A

Bond breaking in which the shared electrons go to one atom

22
Q

Polymerisation

A

Joining together of small molecules to form a large molecule

23
Q

Primary alcohol

A

An alcohol which has only one carbon directly attached to the same carbon as the OH group (except methanol)

24
Q

Secondary alcohol

A

An alcohol which has 2 carbons directly attached to the same carbon as the OH group

25
Q

Tertiary Alcohol

A

An alcohol which has 3 carbons directly attached to the same carbon as the OH group

26
Q

Nucleophile

A

An ion or molecule with a lone pair of electrons that attacks regions of low electron density

27
Q

Hydrolysis

A

Breaking up of molecules by reaction with water

28
Q

Elimination

A

A reaction in which a small molecule is removed from a larger molecule

29
Q

Miscibility

A

Liquids which mix in all proportions ie form a single layer

30
Q

Esterification

A

A reaction between an alcohol and a carboxylic acid or acyl chloride to produce an ester