Definitions Flashcards

1
Q

Define Relative atomic mass

A

Mean mass of an atom relative to 1/12th the mass of an atom of carbon-12

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2
Q

Relative Molecular mass

A

Mean mass of a molecule relative to 1/12th the mass of an atom of carbon-12

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3
Q

Relative isotopic mass

A

The mass of one atom of an isotope relative to 1/12th of the mass of an atom of carbon-12

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4
Q

First ionisation energy

A

Energy required for the removal of one mole of electrons from one mole of atoms to form one mole of gaseous 1+ ions

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5
Q

Orbital

A

A volume of space where there is a high chance of finding an electron. Orbitals contain 2 electrons that spin in opposite directions

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6
Q

Ionic bonding

A

The strong electrostatic attraction between oppositely charged ions

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7
Q

Covalent bond

A

Strong electrostatic attraction between two nuclei and the shared pair of electrons between them

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8
Q

Electronegativity

A

The power of an atom to attract the bonding pair of electrons in a covalent bond

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9
Q

Metallic bonding

A

The strong electrostatic attraction between metal ions and delocalised electrons

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10
Q

What is a Dative/Coordinate Bond

A

Both electrons in a covalent bond come from one atom

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11
Q

Define Oxidation number

A

An oxidation state/number shows the charge on an atom if all of its bonds were considered totally ionic

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12
Q

What is disproportionation

A

An element in a single species is simultaneous oxidised and reduced

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13
Q

Define enthalpy change

A

Enthalpy change is the heat change in a reaction at constant pressure

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14
Q

What are standard conditions for pressure and temperature

A

100 kPa and 298 K

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15
Q

Define enthalpy change of reaction

A

Enthalpy change of a reaction according to the molar quantities in the equation under standard conditions

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16
Q

Define enthalpy change of formation

A

Enthalpy change when one mole of substance is formed from elements in their standard states under standard conditions

17
Q

Define enthalpy change of combustion

A

Enthalpy change when one mole of substance completely combusts in oxygen to form CO2 and H2O under standard conditions

18
Q

Define enthalpy change of neutralisation

A

The enthalpy change when and acid and alkali react to form 1 mole of water under standard conditions

19
Q

Define bond enthalpy

A

Energy required to break one mole of a bond type in a molecule in the gaseous state

20
Q

Define dynamic equilibrium

A

Rate of forwards and backwards reaction is the same. Concentration of reactants and products are constant

21
Q

Define lattice enthalpy of formation

A

Enthalpy change when 1 mole of a solid ionic compound is formed from its gaseous ions under standard conditions

22
Q

Define enthalpy change of atomisation with an example equation for Fluorine

A

The enthalpy change when 1 mole of gaseous atoms is made from an element in its standard state
1/2 F2 (g) —-> F(g)

23
Q

Define first electron affinity

A

The enthalpy change when 1 mole of gaseous 1- ions are made from 1 mole of gaseous atoms.

24
Q

Define 2nd electron affinity

A

The enthalpy change when 1 mole of gaseous 2- ions are made from 1 mole of gaseous 1- ions