Definitions Flashcards
Empirical Formula
A formula which shows the simplest whole number ratio of each element in a compound
Molecular Formula
A formula which shows the actual number of atoms of each element in a molecule
Molar Gas Volume
The volume of one mole of gas nder spec cond of temp and pressure e.g 24dm3 at 20 degress (293K) and 1atm
Percentage Yield
Actual/ Theoretical x100
Atom Economy
Mass of desired product/ total mass of pr x100
Homologous Series
Compounds which have the same gen form, similar chem properties, show a gradation in physical prop and suc members differ by a CH2 unit
Functional Group
R group within a compound
Structural Isomers
Mol which have the same mol form but a dif structural form
Geometric Isomer
Mol with the same str formula but different arrangement of atoms due to the presence of 1/more C=C
Sat Hydrocarbon
Contains no C=C/ C—C bond
Hydrocarbon
Cont H2 and C only
Substitution
Replacing one atom or group with a different atom or group
Homolytic Fission
Bond breaking in which one of the shared e goes to each atom
Heterolytic Fission
Bond breaking in which both e in the shared pair go to a single atom
Radical
A particle with an unpaired e
Unsat Hydrocarbon
Contains at least one C=C or C—C bond
Sigma Bond
A cov bond formed by the linear overlap of atomic orbitals
Pi Bond
A cov bond formed by the sidways overlap of p orbitals
Bond L
The dist between the nuclei of 2 cov bonded atoms
Hydrogenation
Addition of H2 mol across a C=C
Electrophile
An ion or molecule that attacks regions of high e density
Primary Carbocation
A carbocation which ahs one C atom directly bonded to the pos charged C
Sec Carbocation
A carbocat which has 2 C atoms directly bonded to the pos charged C
Tert Carbocation
A carbocat which has 3 C atoms directly bonded to the pos charged C
Polymerisation
Joining together of many small mol (monomers) to form a large mol
Monomers
Many small mol which join together to form a polymer
Polymer
A large mol formed when monomers join together
Primary Halogenoalkane
A halogenoalkane which has one C atom directly bonded to the C atom that is bonded to the halogen
Sec Halogenoalkane
A halogenoalk which has 2 C atoms directly bonded to the C atom that is bonded to the halogen
Tertiary Haloalkane
A halogenoalk which has 3 C atoms directly bonded to the C atom that is bonded to the halogen
Reflux
Repeated boiling and condensing of a r mixture
Hydrolysis
Breaking up mol by r with water
Nucleophile
An ion/ mol with a lone pair of e that attacks regions of low e density
Elimination
A r in which a small mol is removed from a larger mol
Miscibility
L which mix in all proportions i.e form a single layer
Primary Alc
An alc which has one C atom directly bonded to the C atom that is bonded to the -Oh group
Sec Alc
An alc in which two C atoms are directly bonded to the C atom that is directly bonded to the -OH group
Tertiary Alc
An alc in which 3 C atoms are directly bonded to the C atom that is bonded to the -OH group
Ground State
A molecular vibration which is in the lowest poss en state
Wavenumber
the reciprocal of the wavelength and it is measured in cm-1
Endothermic
A r in which the enthalpy of the p is greater than the enthalpy of the r
Exothermic
A r in which the enthalpy of the r is greater than the enthalpy of the p
Standard Cond
298K and 100KPa
Standard Enthalpy Change
Change in heat energy at constant pressure, measured at standard conditions
Standard enthalpy of combustion
The enthalpy change when one mole of a subst is burnt completely in O2 under standard cond
Standard Enthalpy of Formation
The enthalpy change when one mole of a compound is formed from its elements under standard cond
Standard Enthalpy of Neutralisation
The enthalpy change when one mole of water is produced in a neutralisation r under standard cond
Conservation of En
En cannot be created/ destroyed but it can change from one form to another
Hess’ Law
Enthalpy change for a reaction is independent of the route taken provided the initial and final conditions are the same
Average Bond Enthalpy
The energy required to break one mole of a given bond averaged over many compounds
R rate
the change of the conc (amount) of a r/p with respect to time
Catalyst
A subst which increases the rate of a chem r but does not get used up
Activ En
The min amount of en req for a r to occur
Reversible R
A r which goes in both fw and bw dir
Dynamic Equ
Rate of fw r = rate of bw r
Equilibrium
A rev reaction in which the amount of each r/ p remains constant
Homogeneous
A r in which all the r and p remain constant
Heterogeneous
A r in which all the r and p are not in the same physical state
S block el
an el which has an atom with highest en/ outer e in an s-subshell (orbital)
Solubility
the max mass of solute that will dis in 100g solvent at a stated temp