definitions Flashcards

1
Q

atomic number

A

no. of protons

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2
Q

mass number

A

total no. of protons and neutrons

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3
Q

isotopes

A

atoms with the same number of protons but a different number of neutrons

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4
Q

TOF mass spectrometer

A

analytical instrument that gives accurate information about relative isotopic mass and relative abundance of isotopes

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5
Q

electrospray ionisation?

A
high voltage applied to sample 
dissolved in a polar solvent 
molecules lose an electron
form gaseous 1+ ions
must be ionised so they can be accelerated towards negatively charged plate
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6
Q

relative mass

A

the weighted mean mass of an atom of an element relative to 1/12 of the mass of one atom of carbon-12

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7
Q

first ionisation energy

A

the energy required to remove an electron from each atom in one mole of gaseous atoms

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8
Q

what is an acid?

A

a species that is a proton donor

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9
Q

activation energy?

A

the minimum energy required to start a reaction by the breaking of bonds

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10
Q

addition polymer

A

the process in which unsaturated alkene molecules add on to a growing polymer chain one at a time to form a very long saturated molecule chain

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11
Q

addition reaction

A

a reaction in which a reactant is added to an unsaturated molecule to make a saturated molecule

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12
Q

adsorption

A

the process that occurs when a gas liquid or solid is held to the surface of a solid (RARELY A LIQUID)

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13
Q

alkali?

A

a type of base that dissolves in water forming hydroxide ions

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14
Q

alkanes?

A

the homologous series with the general formula cnH2n+2

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15
Q

alkyl group?

A

an alkane with a hydrogen ion removed

alkyl groups are often shown as ‘R’

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16
Q

what does anhydrous mean?

A

substance containing no water molecules

17
Q

what is an anion?

A

a negatively charged ion

18
Q

atom economy?

A

molecule mass of the desired product/sum of molecular masses of all products x 100

19
Q

atomic orbital?

A

a region within an atom that can hold up to two electrons with opposite spins

20
Q

average bond enthalpy?

A

the average enthalpy change that takes place when breaking, by homolytic fission, 1 mol of a given type of bond in the molecules of a gaseous substance

21
Q

avogadro constant?

A

6.022 x 10^23

22
Q

what is a base?

A

species that is a proton acceptor

23
Q

bond enthalpy

A

the enthalpy change that takes place when breaking, by homolytic fission, 1 mol of a given bond in the molecules of a gaseous species

24
Q

catalyst?

A

a substance that increases the rate of a chemical reaction without being used up

25
Q

cation?

A

positively charged ion

26
Q

cis - trans isomerism?

A

type of E/Z isomerism in which there is a non-hydrogen group and a hydrogen on each side of a C=C double bond:
the cis isomer has the H atom of each carbon on the same side
the trans has the H atom of each carbon on different sides

27
Q

concnetration?

A

amount of solute in solvent

mol per dm^2

28
Q

coordinate bond / dative covalent bond

A

a shared pair of electrons which has only been provided by one of the bonding atoms

29
Q

covalent bond?

A

bond formed by a shared pair of electrons

30
Q

what is cracking?

A

the breakdown of long-chained saturated hydrocarbons to form a mixture of shorter-chained alkanes and alkenes

31
Q

what is dehydration?

A

an elimination reaction in which water is removed from a saturated molecule to make an unsaturated molecule