Definitions Flashcards

1
Q

Define First electron affinity:

A

the enthalpy change that takes place when one electron is added to each atom in one mole of gaseous atoms to form one mole of gaseous 1- ions

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2
Q

Define Relative Isotopic mass

A

Average mass of an atom of an isotope relative to 1/12th of the mass of an atom of carbon-12.

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3
Q

Define relative Atomic mass

A

Average mass of an atom of an element, relative to 1/12th of the mass of an atom of carbon-12.

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4
Q

Define the First ionisation energy

A

The energy required to remove 1 mole of electrons from each atom in 1 moles of gaseous atoms to from 1 mole of gaseous 1+ ions

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5
Q

Define 2nd ionisation energy

A

The energy required to remove 1 mole of electrons from each ion in 1 moles of gaseous 1+ ions to form 1 moles of gaseous 2+ ions

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6
Q

Define Ionic bonding

A

Strong electrostatic attraction between two oppositely charged ions. .

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7
Q

Define covalent bonding

A

The strong electrostatic attraction between two nuclei and the shared pair of electrons between them

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8
Q

Define Dative bonding

A

Occurs when one atom donates both electrons in a bond

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9
Q

What is a sigma bond ?

A

A bond that results from a direct overlap of two orbitals.

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10
Q

What is a Pi bond?

A

A bond that is formed when two orbitals overlap sideways

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11
Q

Define Electronegativity and examples of the most electronegative elements

A

The ability of atom to attract the bonding electrons in a covalent bond
- N, O , F most electronegative with a high nuclear charge

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12
Q

Define a dipole

A

Difference in charge between the two atoms of a covalent bond caused by a shift in electron
density in the bond due to the electronegativity difference between elements participating in
bonding

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13
Q

Define Metallic bonding

A

Strong electrostatic attraction between metal ions and the sea of delocalised electrons that surround them.

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14
Q

Describe and explain London forces

A

Weak intermolecular forces between a partially charged covalent molecule, causing a constant shift in electron clouds and asymmetrical electron distribution and becomes and instantaneous dipole .
The strength of London forces depend on the size , shape and number of electrons the atoms have.

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15
Q

Describe and explain permanent -permanent dipole interactions

A

Dipole-dipole attractions between polar or ionic molecules. Stronger than London forces

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16
Q

Describe and explain hydrogen bonds

A

A type of intermolecular force between a hydrogen
bonded to a more electronegative atom than hydrogen like nitrogen, oxygen or fluorine.
Is the strongest intermolecular force

17
Q

define the term orbital

A

a region around the nucleus where there is a high probability of finding an electron