Definitions Flashcards
Define First electron affinity:
the enthalpy change that takes place when one electron is added to each atom in one mole of gaseous atoms to form one mole of gaseous 1- ions
Define Relative Isotopic mass
Average mass of an atom of an isotope relative to 1/12th of the mass of an atom of carbon-12.
Define relative Atomic mass
Average mass of an atom of an element, relative to 1/12th of the mass of an atom of carbon-12.
Define the First ionisation energy
The energy required to remove 1 mole of electrons from each atom in 1 moles of gaseous atoms to from 1 mole of gaseous 1+ ions
Define 2nd ionisation energy
The energy required to remove 1 mole of electrons from each ion in 1 moles of gaseous 1+ ions to form 1 moles of gaseous 2+ ions
Define Ionic bonding
Strong electrostatic attraction between two oppositely charged ions. .
Define covalent bonding
The strong electrostatic attraction between two nuclei and the shared pair of electrons between them
Define Dative bonding
Occurs when one atom donates both electrons in a bond
What is a sigma bond ?
A bond that results from a direct overlap of two orbitals.
What is a Pi bond?
A bond that is formed when two orbitals overlap sideways
Define Electronegativity and examples of the most electronegative elements
The ability of atom to attract the bonding electrons in a covalent bond
- N, O , F most electronegative with a high nuclear charge
Define a dipole
Difference in charge between the two atoms of a covalent bond caused by a shift in electron
density in the bond due to the electronegativity difference between elements participating in
bonding
Define Metallic bonding
Strong electrostatic attraction between metal ions and the sea of delocalised electrons that surround them.
Describe and explain London forces
Weak intermolecular forces between a partially charged covalent molecule, causing a constant shift in electron clouds and asymmetrical electron distribution and becomes and instantaneous dipole .
The strength of London forces depend on the size , shape and number of electrons the atoms have.
Describe and explain permanent -permanent dipole interactions
Dipole-dipole attractions between polar or ionic molecules. Stronger than London forces