Crystal Structure Flashcards
Two Types of Solid
Crystalline and Amorphous
Properties of crystalline solids depend on the _________ or the manner in which
atoms, ions, or molecules are spatially arranged
crystal
structure of the material,
is a periodic arrangement of
points in space with respect to three dimensional
network of lines
Space Lattice or Lattice
________ – the space covered by the lattice
points
Lattice Space
_______ – each atom represented by a point,
where the network lines intersect
Lattice Point
________ arrangement of lattice points
Lattice Array
________ Tiny blocks formed by arrangements of small
groups of atoms
Unit Cell
Chosen to represent the symmetry of a crystal
structure, and may be defined as:
- Finite representation of infinite lattice
- Small repeat entity
- Basic structural unit
- Building block of crystal structure
Lattice Parameters
Six lattice parameters are: ____________
Typically in the order of few Angstroms (Å), equal to
__________
Based on the length equality or inequality and the
orientation (the angles between them, α, β, and γ) a
total of _________ can be defined
a, b, c, α, β, and γ.
0.1 nanometer
7 crystal systems
Bravais Lattices
____ types of crystal
systems where
presented, with the
inclusion of the
property of Centering
Types of Centering
___________
14
1. Face-Centered
2. Body-Centered
3. Base-Centered
______________
* Atoms are arranged at the corners of the cube
with another atom at the cube center
*
Has 2 atoms in one unit cell.
* Examples: alpha iron, chromium, tungsten, tantalum,
and molybdenum
» Center and corner atoms touch one another along
cube diagonals, and unit cell length o and atomic
Body-Centered Cubic (BCC)
_________
Most elementary crystal structure with
three mutually perpendicular axes
arbitrarily placed through one of the
corners of a cell.
Each corner is occupied with ____
Only _____ is packed in this
manner
Packing density is relatively ______
Simple Cubic (SC)
one atom
polonium
low
Hexagonal Closed-Pack (HCP)
Cell of an HCP lattice is visualized as a top and
bottom plane of ______, forming a regular hexagon
around a central atom. In between, these planes is a
half-hexagon of _________. D
There are two lattice parameters in HCP, a and c,
representing the basal and height parameters
☐ respectively.
AU
Has ______ per unit cell.
Examples: zinc, lithium, magnesium, beryllium
7 atoms
3 atoms
6 atoms
_______
a line or vector directed between
two points
directions are given by specifying
the coordinates (x, y, z) of a point on
a vector (Pxyz) passing through the
origin
Notation: ______
Crystallographic Direction
[xyz]
__________ is the number of nearest neighbor atoms or ions surrounding an atom or ion. For
FCC and HCP systems, the coordination number is ____. For BCC, it’s__. For SC, coordination number is
____.
Coordination number
12
8
6