Covalent Bonding Characteristics Flashcards
What is bond length?
Distance between the nuclei of the two atoms in a bond
- The larger the atoms in a bond, the longer their bond length
What is bond order?
Number of electron pairs shared between the atoms.
- Single bond = 1 electron pair
- Double bond = 2 electron pairs
- Triple bond = 3 electron pairs
When comparing bonds between the same two atoms…?
A higher bond order usually has a shorter but stronger bond.
ex: double bonds have a higher order than single bonds, thus double bonds are shorter but stronger
What is bond strength?
The amount of energy required to break a covalent bond
What is bond dissociation energy?
The change in enthalpy when one mole of a bond in a covalent molecule in a gas phase is broken, resulting in gaseous fragments. It also varies based on bond order type and atoms involved in the bond order
Formation of bonds from gaseous atom is always what?
Exothermic; releasing energy
Breaking bonds is always what?
Endothermic; absorbing energy
What happens as bond order increases in between the same elements?
Bond dissociation energy increases, bond length decreases
What makes bond strength?
Bond order and bond dissociation energy. A shorter bond does not always mean a stronger bond, it depends on the two factors above