Corrosion 2 Flashcards
a device that can generate electrical
energy from the chemical reactions occurring in it, or use the
electrical energy supplied to it to facilitate chemical reactions in
it. These devices are capable of converting chemical energy into
electrical energy, or vice versa
electrochemical cell
defined as the deterioration of materials by chemical processes. Of
these, the most important by far is electrochemical corrosion of metals.
Corrosion
can be regarded as a short-circuited electrochemical ce
corrosion system
also called “dissimilar metal corrosion” or wrongly
“electrolysis”) refers to corrosion damage induced when
two dissimilar materials are coupled in a corrosive
electrolyte.
galvanic corrosion
late 18th century- The
bimetallic driving force was
discovered through as series
of experiments with the
exposed muscles and nerves
of a frog that contracted
when connected to a
bimetallic conductor.
Luigi Galvani
1800- the principle was later
put into a practical
application by first electrical
cell, or battery: a series of
metal disks of two kinds,
separated by cardboard
disks soaked with acid or salt
solutions.
Alessandro Volta
early 19th century- The
principle was also
engineered into the useful
protection of metallic
structures
Sir Humphry Davy
the metal that corrodes preferentially. It loses
electrons and experiences oxidation. LESS NOBLE
Anode
metal that is protected from corrosion. It
receives electrons and undergoes reduction. MORE NOBLE
Cathode
A conductive solution, like saltwater or even tap
water, that allows the flow of ions between the anode and
cathode.
Electrolyte
A metallic pathway connecting the
anode and cathode, allowing the flow of electrons to
complete the circuit
Electrical connection:
Choosing compatible metals with minimal
differences in nobility when possible can
significantly reduce the risk.
Material selection
Physically isolating the dissimilar metals using
non-conductive materials like plastic or rubber
can prevent electrical contact and halt the
corrosion process.
Electrical isolation
Applying protective coatings to the anode can
create a barrier and impede its interaction with the
electrolyte.
Coating
ntroducing a more active metal, called a
sacrificial anode, can be strategically placed to
corrode preferentially and protect the desired
metal. This principle is used in cathodic protection
systems for pipelines and other structures
Sacrificial anodes