Contaminant Fate and Transport Flashcards

1
Q

3 phases of transport

A
  1. Air
  2. Soil
  3. Water
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2
Q

Rate from fastest to slowest

A

Fastest:

  1. air diffusion
  2. water diffusion
  3. soil diffusion
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3
Q

Mechanism controlling the transport of dissolved contaminants in aquifers (3)

A
  1. Advection
  2. Mechanical dispersion
  3. Diffusion
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4
Q

Advection definition

A
  • Transfer of matter in a fluid, especially horizontally in the atmosphere or the sea
  • Useful equation: darcy’s law
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5
Q

Mechanical Dispersion definition

A
  • Spreading of a solute as it moves through porous media
  • Directly related to groundwater velocity
  • Mixing is due to tortuosity
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6
Q

Diffusion definition

A

-Random molecular movement due to concentration gradient

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7
Q

Diffusion: molecular weight vs. diffusivity

A

High MW = Low diffusivity

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8
Q

Tortuosity vs. dispersion vs. material sorting

A

Poorly sorted = high tortuosity, more dispersion

Well sorted = low tortuosity, less dispersion

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9
Q

Plume (Mechanical Dispersion)

A

Distribution and extent of contaminants migrating in the subsurface

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10
Q

DNAPL

A
  • Dense nonaqueous phase liquids

- Higher density than water

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11
Q

Dispersion

A

The spreading of a solute as it travels through porous media

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12
Q

LNAPL

A
  • Light nonaqueous phase liquid
  • lower density than water
  • ex: petrol, will float on top of water table
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13
Q

NAPL

A
  • non-acqueous phase liquid

- low solubility compounds - will not dissolve easily in water

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