Constitution of Alloys Flashcards
a substance that has metallic properties and is composed of two or more chemical elements, one of which is a metal
alloy
what are the two alloy systems
binary alloy system, ternary alloy system
- made up of two elements
binary alloy system
- made up of three elements
ternary alloy system
What are the classification of alloys?
homogenous, mixture
consist of single phase
homogenous
combination of several phases
mixture
what are the possible phases in the solid state
pure metal, intermediate or compound, solid solutions
Under equilibrium conditions, all metals exhibit a definite melting or freezing point.
*under equilibrium conditions - implies extremely slow heating and cooling
pure metal
phases whose chemical compositions are intermediate between the two pure metals and have crystal structures different from those of the pure metals
When a compound is formed, the elements lose their individual identity and characteristic properties to a large extent.
intermediate or compound
cooling curve for a compound
congruent melting phase
what are the most common intermediate alloys
Intermetallic Compounds or Valency Compounds, Interstitial Compounds, Electron Compounds,
formed between chemically dissimilar metals and have strong bonding with nonmetallic properties
Intermetallic Compounds or Valency Compounds
formed between transition metals such as Sc, Ti, W, Fe, Ta with H, O, C, Ni, B - metallic in properties with high melting points and hard
Interstitial Compounds
formed between systems with similar lattice structures and definite ratio of valence electrons to atoms
Electron Compounds
have properties resembling those of solid solutions such as wide range of composition, high ductility and low hardness
Electron Compounds
- a solution in the solid state and consists of two kinds of atoms combined in one type of space lattice
- solidify over a range in temperature
Solid Solutions
What are the types of solid solutions?
Substitutional Solid Solution, interstitial solid solution
the atoms of the solute substitute for atoms of the solvent in the lattice of the solvent
Substitutional Solid Solution
- formed when atoms of small atomic radii fit into the spaces or interstices of the lattice structure of the larger solvent atoms (atomic radii of less than 1 angstrom such as H, B, C, N, O)
- differs from interstitial compounds in that the amount of smaller atoms required to form the compound is greater than the amount that may be dissolved interstitially
- have very limited solubility and are of little importance
Interstitial Solid Solution
Factors under substitutional solid solution
Crystal-structure , relative size, chemical affinity, relative valence
favorable when the difference in atomic radii is greater than 8%and less than about 15%
Relative-size
favorable when the difference in atomic radii is greater than 8%and less than about 15%
Relative-size
the farther apart the elements in the periodic table, the greater it is
Chemical-affinity
metal of lower valence tends to dissolve more of a metal of higher valence than vice versa
relative valence