concrete technology Flashcards
characteristics and specifications of OPC
- Lime saturation Factor is limited between i.e. 0.66 to 1.02.
- Free lime-cause the Cement to be unsound.
- Percentage of (AL2O3/Fe2O3) is not less than 0.66.
- Insoluble residue not more than 1.5%.
- Percentage of SO3 limited by 2.5% when C3A < 7% and not more than 3% when C3A >7%.
- Loss of ignition -4%(max)
- Percentage of Mg0-5% (max.)
- Fineness -not less than 2250 cm2/g.
Rapid hardening Portland cement
- It is firmer than Ordinary Portland Cement
- It contains more C3S are less C2S than the ordinary Portland cement.
- Its 3 days strength is same as 7 days strength of ordinary Portland cement.
Low heat Portland cement
- Heat generated in ordinary Portland cement at the end of 3days 80 cal/gm. While in low heat cement it is about 50cal/gm of cement.
- It has low percentage of C3A and relatively more C2S and less C3S than O.P. Cement.
- Reduce and delay the heat of hydration. British standard ( B S. 1370 : 1974 ) limit the heat of hydration of this cement.
Sulphate resisting Portland cement
and super sulphated cement
• Maximum C3A content by 3.5% and minimum fineness by 2500 cm’/g.
• Firmer than ordinary pot land cement.
• Sulphate forms the sulpha-aluminates which have expensive properties and so causes disintegration of concrete.
SUPER SULPHATED
• For this cement, the silage as obtained from blast furnace is used
• The clinkers of cement are ground with about 60 to 65 percent of slag.
• Its strength in early days is less and hence it required longer curing period. It proves to be economical as slag, which is a Waste product, is used in its manufactures.
Pozzolanic cement
- As per Indian standard, the proportions of Pozzolana may be 10 to 25 % by weight. e.2. Burnt clay, shale, Fly ash.
- This Cement has higher resistance to chemical agencies and to sea water because of absence of lime.
- It evolves less heat and initial strength is less but final strength is 28 days onward equal to ordinary Portland cement.
- It possesses less resistance to the erosion and weathering action.
- It imparts higher degree of water tightness and it is cheap.
White Portland cement
- Grey colour of O.P. cement is due to presence of Iron Oxide. Hence in White Cement Fe,,O, is limited to 1 %. Sodium Alumina Ferrite (Crinoline) NavAlF6 is added to act as flux in the absence of Iron-Oxide. •: • It is quick drying, possesses high strength and has superior aesthetic values and it also cost lee than ordinary Cement because of specific requirements imposed upon the raw materials and the manufacturing process.
- White Cement are used in Swimming pools, for painting garden furniture, moulding sculptures and statues etc.
Coloured Portland
- The Cement of desired colour may be obtained by mixing mineral pigments with ordinary Cement.
- The amount of colouring material may vary from 5 to 10 percent. If this percentage exceeds 10percent, the strength of cements is affected.
- The iron Oxide in different proportions gives brown, red or yellow colour. The coloured Cement are widely used for finishing of floors, window sill slabs, stair treads etc.
Expansive cement
- This type of cement is produced by adding an expanding medium like sulphoaluminate and a stabilising agent to the ordinary cement.
- The expanding cement is used for the construction of water retaining structures and for repairing the damaged concrete surfaces.
High alumina cement
- This cement is produced by grilling clinkers formed by calcining bauxite and lime. It can stand high temper lures.
- If evolves great heat during setting. It is therefore not affected by frost
- high resistance in case of chemical corrosion
Bogue’s compound values
C3s - 30-50 %
C2S : 20-45 %
C3A : 8-12%
C4AF : 6-10%
Calcium hydroxide in cement
It constitutes 20 to 25 per cent of the volume of solids
The calcium hydroxide also reacts with sulphates present in soils or water to form calcium sulphate which further reacts with C3A . This is known as sulphate attack.
Compressive strength test of cement
- This test is carried out to determine the compressive strength of cement.
- The mortar of cement and sand is prepared in ratio 1:3.
- Water is added to mortar in water content p/4 +3.
- The mortar is placed in moulds.The test specimens are in the form of cubes and the moulds are of metals.For 70.6 mm and 76 mm cubes ,the cement required is 185gm and 235 gm respectively.
- Then the mortar is compacted in vibrating machine for 2 minutes and the moulds are placed in a damp cabin for 24 hours.
- Then are submerged in clean water for curing.
- The cubes are then tested in compression testing machine at the end of 3days and 7 days.
consistency of cement
- Take 300 gm of cement and add 30 percent by weight or 90 gm of water to it.
- Fill the mould of Vicat apparatus and the gauging time should be 3.75 to 4.25 minutes.
- Vicat apparatus consists of aneedle is attached a movable rod with an indicator attached to it.
- There are three attachments: square needle,plungerand needle with annular collar.
- The plunger is attached to the movable rod.the plunger is gently lowered on the paste in the mould.
- The settlement of plunger is noted.If the penetration is between 5 mm to 7 mm from the bottom of mould,the water added is correct.If not process is repeated with different percentages of water till the desired penetration is obtained.
Setting time test of cement
- Square needle is attached to moving rod of vicat apparatus.
- The needle is quickly released and it is allowed to penetrate the cement paste.In the beginning the needle penetrates completely.The procedure is repeated at regular intervals till the needle does not penetrate completely.(upto 5mm from bottom)
- Initial setting time =<30min for ordinary Portland cement and 60 min for low heat cement.
- The cement paste is prepared as above and it is filled in the Vicat mould.
- The needle with annular collar is attached to the moving rod of the Vicat apparatus.
- The needle is gently released. The time at which the needle makes an impression on test block and the collar fails to do so is noted.
- Final setting time is the difference between the time at which water was added to cement and time as recorded in previous step,and it is =<10hours.
Soundness test of cement
- The purpose of this test is to detect the presence of uncombined lime in the cement.
- It is covered at top by another glass plate. A small weight is placed at top and the whole assembly is submerged in water for 24 hours.
- The distance between the points of indicator is noted.The mould is again placed in water and heat is applied in such a way that boiling point of water is reached in about 30 minutes. The boiling of water is continued for one hour.
- The mould is removed from water and it is allowed to cool down.
- The distance between the points of indicator is again measured.The difference between the two readings indicates the expansion of cement and it should not exceed 10 mm.
bulking of sand
5-8 % water content
increase in volume 20-40 %
Guniting
method used for repairing of concrete work
1:3 mixture of cement sand
calcination
heating of lime to redness in open air
hydraulicity
property of lime by which it sets or hardens where there is no free air circulation
quick lime
CaO obtained from calcination.
capable of slaking in presence of water
Fat lime
high calcium lime, pure lime, rich lime or white lime
it slake vigorously and volume can be increased 2~2.5 times
Impurity < 5%
Hydraulic lime
also called as water lime as it sets under water
it contains clay and some amount of ferrous oxide