Composites- Manufacturing 1 Flashcards

1
Q

Generic strategy for manufacturing composites

A

The fibre and matrix must be maintained at the correct shape, temperature and pressure throughout both the process and part

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2
Q

How does shape of fibres dictate manufacturing route?

A

Short fibres can effectively be processed like plastic additives whereas long fibres need dedicated processing techniques

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3
Q

How does choice of matrix dictate manufacturing route?

A

Thermoplastics have a higher viscosity in molten state than most thermoset polymers making them harder to combine with reinforcements

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4
Q

How does viscosity influence what is required to generate flow?

A

High viscosity matrices require high forces making it harder to combine with fibres.
Low viscosity matrices require low forces making it easier to combine with fibres.

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5
Q

Standard approaches for processing high viscosity composites

A

Like short fibres in thermoplastic melts. Use high forces. Primary examples are injection moulding, extrusion and hot pressing. Alternative is to use short flow distance. Primary examples are powder processing, co-mingling and hot pressing.

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6
Q

Advantage of using thermoplastics in terms of storage

A

Despite being harder to combine with reinforcements, once combination has been achieved, thermoplastic composites systems are stable and can be stored for many months or years prior to part manufacture

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7
Q

Standard approaches for processing low viscosity composites

A

Like thermosetting resins. More easily combined with fibres so low force processing routes preferred. Primary examples are wet lay-up, pultrusion, filament winding, RTM, pre-preg lay-up, compression moulding. It is possible to bleed resin out of the fibres if too high a force is used. Higher forces can be applied after the resin becomes solidified

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8
Q

Storage disadvantage of low viscosity resins

A

Combining them with fibres is relatively easy but it’s also easy for the two phases to separate so storage options are limited and resin is generally cured immediately

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9
Q

Powder processing

A

Used for thermoplastic and thermoset. Some matrices available as powders. E.g UHMWPE thermoplastic or phenolics thermoset. These can be processed by mixing the powder with the reinforcement by a low energy mixing method. Hot pressing then melts or reacts the matrix to form the solid composite. Minimal resin flow is required

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10
Q

Hot pressing

A

Prepared mixtures of reinforcement and matrix can be hot pressed. Apply pressure and temperature over time. Can use thermoplastic sheets like GMT or thermosetting moulding compounds. Applications are large, flat or moderately curved parts such as car body panels, dashboard panels and component cases. Basically press down on the prepared mixture to force it into shape between plates. Flash can be released out sides

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11
Q

Injection moulding

A

Used to make particle or short fibre reinforced thermoplastic or thermosetting polymer composites. Much easier with thermoplastics. Feed in the resin into a barrel and force it to other end using a rotating screw. Screw presses it against barrel more as goes along and it melts (thermoplastic) until it is injected into a mould. Barrel must be cooled with thermosets. Applications often small, intricate parts like high T resistant electrical parts with a phenolic matrix

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12
Q

The 5 generic steps common to thermoset composite manufacturing processes

A
  1. Preparing the fibres and matrix
  2. Combining the fibres and matrix
  3. Void removal
  4. Consolidation
  5. Resin curing
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13
Q

Preparing the fibres

A

Unidirectional cloth, woven fabrics and randomly aligned mats all need cutting to shape and size. Process can be automated using computer controlled ply-cutters. Required plies are given in a ply book

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14
Q

Preparing the matrix

A

Weigh resin first as is often the most viscous and harder to measure accurately. Mix in curing agents at the required ratio. Often use an equivalent weight which allows the correct molar ratio to be used. E.g epoxy equivalent weight (EEW). Note the pot life which starts when curing agents are mixed in

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15
Q

Preparing the fibres (preforms)

A

Preforms are dry fibres arranged into correct shape, size, thickness and fibre orientation prior to resin injection. Often used in RTM and made by specialist preform manufacturers. Most traditional textile/fabric processes can be used to produce preforms. Like winding, weaving and stitching, braiding and knitting.

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16
Q

Ways of combining the fibres and matrix

A

Often intrinsically part of the particular processing technique although could use pre-prepared moulding compounds or pre-preg. For handling liquid resin use:
Wet lay-up (hand or spray)
Pultrusion
Filament winding
Resin transfer moulding (RTM)

17
Q

Moulding compounds

A

Pre-mixed fibre, matrix and filler. Typical recipe is 25% unsaturated polyester, 20% chopped E glass fibre, 55% filler (usually CaCO3 or MgO). Sold as sheet moulding compounds (fibres aligned within a sheet) or bulk moulding compounds (fibres less aligned)

18
Q

What is filler for?

A

Used in moulding compounds. Increase dimensional stability. Reduce shrinkage. Reduce cost. Ensure a certain volume is filled

19
Q

What is pre-preg?

A

Where fibres have been pre-impregnated with the resin prior to part manufacture.

20
Q

Staged pre-preg

A

Some thermosetting resins like epoxies can be staged. Mix with the curing agent (A stage) and then immediately impregnate into fibres. Partly cure (stage B) and then freeze to slow reaction down. Resin still flexible but won’t separate from fibres. Then pre-preg can be rolled up and stored.

21
Q

Storage and use of pre-preg

A

B stage resin remains partly cured for weeks or months as long as temperature kept low enough. Often kept in freezer (-18C). Shelf life often 12 months for certified aerospace pre-pregs though they can be used for quite some time after. To use warm up, open bag and improve tackiness with warm air

22
Q

Why may voids be present in a composite and what problems do they cause?

A

Trapped air in matrix, between fibres/matrix or between plies. Gases generated by resin cure reaction. Poor consolidation. They decrease composite stiffness as they support no load. They decrease composite strength as they create stress concentrations which act as flaws. Therefore void reduction must be done before curing

23
Q

Methods of void removal

A

Vacuum can remove some voids (do at very start before combining with curing agents).
Others can be compressed as much as possible using pressure

24
Q

Vacuum bagging for void removal

A

Flexible transparent sheet placed over composite assembly and sealed. Vacuum applied between the sheet and composite to remove air inside the bag. Creates consolidation pressure of 1atm on the composite and removes any volatiles and some voids

25
Q

What is consolidation?

A

The process of ensuring the composite’s constituent phases are forced together and, as a result, that the composite is fully dense. Achieved by applying pressure.

26
Q

What does lower or higher pressure for consolidation mean for ff and mechanical properties?

A

Low pressure leads to lower ff and so lower mechanical properties.
High pressure leads to higher ff and so higher mechanical properties

27
Q

Autoclave

A

Used for consolidation. A vacuum bag adds 1atm of consolidation pressure. Ideally put entire vacuum bag assembly into an autoclave. Is essentially a large pressure cooker applying pressure and heat. 5-10atm is common

28
Q

What temperatures can curing take place at?

A

Depends on the curing chemistry. Room temperature cured are often lower performance. High temperature cured often higher performance. Some resin reactions are exothermic (e.g epoxy resins with amine curing agents) and so must be controlled.

29
Q

What do phenylene rings in epoxies do?

A

These are in high performance epoxies. Phenylene rings on the polymer chain. Improves stiffness and strength. Gives more control over resin cure

30
Q

How does temperature vary over a cure schedule?

A

Ramp up from RT a bit then constant at void removal. Ramp up quite a bit more (during consolidation) to cure temperature for curing. Cool down back to RT. Might be 350 mins

31
Q

How does vacuum and temperature vary over a curing schedule?

A

Vacuum applied to -1atm during void removal and consolidation. Remove so back to 0atm when curing.
Applied pressure starts at 0 through void removal until consolidation begins where is ramped up steeply to 5-10 atm. Stay here over cure and hold until the temperature is below Tg. Then remove pressure so all back at 0.