Composites Flashcards

1
Q

What is a resin composite?

A

an organic resin matrix bonded with an inorganic filler

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2
Q

What are the different types of filler sizes? why are they spherical?

A

macro, micro, hybrid, modern hybrid, nanocomposites

shape = spherical - less shrinkage

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3
Q

Why is Composite Easy to Use (3)

A

flowable
osmotic
bulk-fill

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4
Q

PROS (5)

A

aesthetics
conserve tooth structure
high compressive and tensile strength
high coefficient of thermal expansion
low thermal conductivity

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5
Q

CONS

A

Technique sensitivity
polymerisation shrinkage

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6
Q

why is polymerisation shrinkage bad? (6)

A

causes secondary caries, sensitivity, lowers wear resistance, marginal leakage, poor retention, staining

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7
Q

in activation, how do you chemically set composites?

A

organic amine + organic peroxide

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8
Q

How is composite set?

A

free radical addition polymerisation

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9
Q

in activation, how do you light cure composite?

A

camphorquinone + blue light (450-490nm)

or

lucirin photo-initiator, absorb light at 410nm

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10
Q

what is the gel point when light curing?

A

the composite is yielding, stress is transferred to tooth

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11
Q

what is the maximum depth to light cure

A

2mm

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12
Q

what are the steps of free radical polymerisation

A

activation
initiation
propagation
termination

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13
Q

what is the resin matrix made of?

A

Bis-GMA, UDMA or TEGMA

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14
Q

Bis-GMA, UDMA and TEGMA are dimethacrylates, what does this mean?

A

C=C bonds on both ends

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15
Q

BIS-GMA is very viscous, how is this lowered?

A

adding TEGMA

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16
Q

properties of Bis-GMA

A

movable
increases polymer conversion
more crosslinking
less shrinkage

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17
Q

How is a resin composite made?

A

add resin matrix
add filler
coupling phase

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18
Q

properties of inorganic fillers (6)

A

reduce:
- shrinkage
- water absorption
- thermal expansion

increase:
- compressive and tensile strength
- modulus of elasticity
- abrasion resistance

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19
Q

What is the coupling phase?

A

chemical bond transferring stress between filler particle and resin

20
Q

what coupling agent is usually used

A

organosilane
- hydroxyl group on filler - siloxane end
- resin - methacrylate end

20
Q

what coupling agent is usually used

A

organosilane
- hydroxyl group on filler - siloxane end
- resin - methacrylate end

21
Q

Pros of coupling agent

A

increase strength

22
Q

cons of coupling agent

A

silane ages quickly
sensitive to water

23
Q

are composites hydrophilic or hydrophobic

A

hydrophobic

24
what pH is etching
0.2
25
what does etching do
decalcifies portions of enamel rods in 5-8 seconds dissolving calcium salts exposing interprismatic areas
26
what bond strength does etching make the composite to the tooth
20MPa
27
is etching true adhesion?
no, it is mechanical bonding
28
why shouldn't the smear layer be kept?
impairs the bond to dentine can harbour bacteria
29
how is the smear layer created
mechanical cutting of dentine
30
why was the smear layer thought to be good?
it would block tubules to prevent bacterial penetration ITS WRONG THO.
31
What is the hybrid layer
infiltration of resin monomers into the collagen fibre matrix of demineralised dentine
32
steps to setting composite (5)
etch primer bonding adhesive apply composite resin cure
33
what is the purpose of etching?
improve retention more surface area remove surface layer allows penetration of bonding agent into dentin
34
what acid is etching?
35-37% phosphoric acid
35
how long should you wait for etching
5 seconds
36
why dont we leave etching on for a long time
exposed collagen fibres in the dentine collapse
37
how do you remove etching
rinse and blot
38
what does a primer do?
improves wettability and penetrates etched dentin tubules
39
what is the primer?
a amphiphilic resin monomer with low viscosity
40
what the the types of primer
acetone, water or ethanol based
41
what is the bonding adhesive?
unfilled/lightly filled resin
42
what does the bonding adhesive do?
bonds to collagen fibres in dentin, forming hybrid layer
43
what is self etch?
acidic monomers that etch and prime dentine don't need to rinse and so it reduces application time and technique sensitivity
44
what does self etch have to do?
dissolve smear layer decalcify intertubular dentine penetrate to embed superficial collagen = produce effective hybrid layer
45
what is the smear layer?
created when tissue is cut with hand or rotary instruments