Composite Resins Flashcards
Under what conditions may a composite restoration be placed into a tooth? (4 points)
- New dental caries
- Abrasion/erosion
- Failed restoration/secondary caries
- Trauma
What are the 5 things contained within composite resins?
- Glass filler particles
- Resin
- Camphorquinone (photo initiator)
- Low weight dimethacrylates
- Silane coupling agent
The filler particles within amalgam can have various types of glass in them. What are 5 examples of these?
- Microfine silica
- Quartz
- Borosilicate glass
- Lithium aluminium silicate
- Barium aluminium silicate
What is the particle size and % volume for <i>conventional</i> composite resin filler particles?
Particle size = 10-40um
% volume = 50
What is the particle size and % volume for <i>Microfine</i> composite resin filler particles?
Particle size = 0.04-0.2um
% volume = 25%
What is the particle size and % volume for <i>Fine</i> composite resin filler particles?
Partical size = 0.5-3um
% volume = 60-70%
What is the particle size and % volume for <i>Hybrid</i> composite resin filler particles?
Particle size = Range (0.01-0.1um and 1-10um)
% volume = 70%
What monomers are used in the resin of composite resins? (2 examples)
- BIS-GMA - reaction product of bisphenol-A and glycidyl methacrylate
- Urethane dimethacrylates
What are the key characteristics of monomers in composite resins? (2 points)
- Difunctional molecule (essential for the cross linking that will be needed for the polymerisation reaction)
- Undergoes free radical addition polymerisation
What is Camphorquinone activated by?
- Blue light (curing light)
What type of molecules does Camphorquinone produce and what do they do?
- Produces radical molecules (that are electrically charged)
- These initiate free radical addition polymerisation of BIS-GMA which leads to chan ges in resin properties
Camphorquinone causes a degree of conversion of resin. What percentage or conversion can it facilitate?
- 35-80% (the rest is unreacted monomer)
Why are low weight dimethacrylates added to composite resins? (2 points)
- Added to adjust viscosity and reactivity
- Slows down the setting of the material
Why is a silane coupling agent used in composite resins? (3 points)
- Good bond between filler particle and resin is essential
- Normally water will adhere to glass filler particles, preventing resin from bonding to the glass surface
- A coupling agent is used to preferentially bond to the glass and also bond to the resin
What are 7 uses of composites?
- Where aesthetics are important
- Class III, IV and V permanent restorations
- Class II - limited occlusal wear
- LAbial veneers
- Inlays, onlays - indirect technique
- Cores
- Modified forms as luting cements (some dual cured)
How would you classify composites? (3 points)
- Filler type
- Curing method (light cured or self cured)
- Area of use:
- Anterior - microfilled, or submicron hybrid
- Posterior - Heavily filled
- Universal - Submicron hybrid
How can you classify a composite in terms of handling characteristics? (3points)
- Condensable
- Syringeable
- Flowable
What is meant by a condensable composite?
- ‘amalgam’ feeling - greater porosity
- (one that yo can pack into a cavity in a similar way to amalgam)
What are the characteristics of a syringeable composite? (3 points)
- good adaption, less porosities and easy to apply
What are the characteristics of a flowable composite? (4 points)
- Lower filler content
- More shrinkage
- Difficult to apply
- Place for them - with fibrous ribbons
What are the effects of adding filler particles to composite resins? (7 points)
- Improved mechanical properties
- Increased aesthetics
- Increased abrasion resistance (less easy to break the surface)
- Lower thermal expansion (still not perfect)
- Lower polymerisation shrinkage
- Less heat of polymerisation
- Some radiopaque
How many pastes are in a self curing composite?
2 pastes
How many pastes are in a UV activation composite resin?
one paste
How many pastes are in a light cure composite resin?
one paste
What happens in self cure composite activation?
Benzoyl peroxide + aromatic tertiary dentine -> free radicals
What happens in light cure composite activation?
Camphorquinone + blue light (430-490nm) -> free radicals
What are the advantages of light curing systems? (6 points)
- Extended working time i.e. on demand set
- Less finishing
- Immediate finishing
- Less waste
- Higher filler levels (not mixing two pastes)
- Less porosity (not mixing two pastes)
When light curing where is most of the light absorbed and what effect does this have?
- Most of blue light is absorbed close to the surface
- Composite resin nearest the surface sets the most readily and becomes hard
What is meant by the ‘ depth of cure’?
- The depth to which the composite resin polymerises sufficien tly (such thaqt its hardness is about half of that of the cured surface)
What is the typical depth of cure of a composite resin?
- 2mm
What does the depth of cure indicate to use when building a restoration?
- Indicates increment thickness to use
- Increment > 2mm results in a under-polymerised base which causes poor bonding to the tooth and early failure
What do bulk fill composites have as well a Camphorquinone?
- Lucerin initiator (requires UV light)