Composite Resin Update - on word doc Flashcards
Components of composite resin.
- Matrix (continuous phase) Comonomer system, of 2-4 monomers
- Filler: dispersed phase (filler particles of different shapes and sizes)
- Coupline agent: internal interface coupling agent (binds filler to matrix)
- Bonding system: external interface coupling agent
and:
- initiatory/accelerator system
- stabilisers (for storage stability)
- pigments (for colour and radiolucency)
What are composite fillers?
glass or ceramic particles that give bulk to the composite material
particle distributions today are designed by computer models - about 80% volume of the material
come in many sizes
What are the different sizes of filler particles? (5) How many are combined in a composite, what does this do? (3)
- macro
- micro
- nano
- nanomere
- nanocluster
higher amount of nanofillers:
- increases translucency (smaller than the wavelength of light)
- reduces polymerisation stress
- combination of many fillers for desired effect
What is polymerisation/shrinkage stress? (not in lec)
as a result of the polymerisation process, the liquid or resin is converted into a solid, which results in a density change that reduces the overall volume - internal load
e.g. nanofillers will likely shrink as much as traditional fillers but create less polymerisations stress
What is polymerisation stress the result of? (4)
- external constraint of the free shrinkage imposed by bonding to tooth structure
- size and nature of the monomers
- acquisition of stiffness during polymerisation
- rate of the reaction
What is the external interface coupling agent?
a bonding system
- includes bonding to enamel, dentine adhesive and bonding agent (unfilled resin)
e.g. dentine adhesive -> self-etching primers -> one bottle bonds (enamel and dentine) -> self-adhesive composite