Composite Flashcards
3 components of composite
1) highly cross-linked polymeric matrix (organic)
2) fillers (inorganic)
3) silane coupling agent
example of polymerization inhibitor
butylated hydroxytoluene (BHT)
high density monomers
Bis-GMA
UDMA
added to bis-GMA to decrease viscosity
TEGDMA
high density makes it ___
viscous and difficult to manipulate
Bis-GMA and UDMA cause increase in what?
increase in:
- polymerization shrinkage
- strength, rigidity
- cross linking
the greater the proportion of diluting monomers, the greater the _____
the greater the polymerization shrinkage
function of fillers
- reinforcement
- reduction of polymerization shrinkage
- reduction of thermal expansion/contraction
- decreased water sorption
- control of workability/viscosity
- imparting radiopacity
quartz
- chemically inert
- abrasive
- hard to grind
- hard to polish
silica
- not crystalline
- not as hard as quartz
- less abrasive and easier to polish
barium
-most common
-radiopacity
-not as inert
slowly leached and weakened in acidity, alkalinity, oral fluids
glass fillers
- attacked by fluoride solutions
- susceptible to abrasive wear
- less lifetime (compared to silica resins)
distribution of fillers
various particle sizes allow max loading (fewer spaces)
coupling agent
bonds filler particles to resin matrix
commonly used coupling agent
organosilanes