Composite Flashcards
uses for composite
primary/secondary caries, abrasion, erosion, trauma
mechanical properties of composite
smooth surface finish/polishable, low setting shrinkage, technique sensitive
chemical properties of composite
thermal expansion coefficient is high, compared to tooth material and GIC/amalgam [bad]
- 25-68ppm *C
under cold stimulus, composite can shrink away from cavosurface margins
thermal conductivity and diffusivity are low [good]
biological properties
biocompatibility is generally low, not usually anti-cariogenic but some release fluoride
components of composite
filler particles, resin, camphorquinone, low weight dimethacrylates, silane coupling agent
filler particles [component]
increase proportion of filler = decreased thermal expansion coefficient [good]
improve mechanical properties of material = strength, rigidity, hardness, abrasion resistance, low polymerisation contraction, greater strength, improved aesthetics
conventionally glass/quartz
resin [component]
monomers are used, a difunctional molecule C=C, facilitates crosslinking and undergoes free radical addition polymerisation
BIS-GMA = bisophenol A and glycidyl methacrylate
comphorquinone [component]
is the blue light activation, releases free radical, allows setting
free radicals bond to BIS-GMA resin which changes resin to increased molecular weight, viscosity and strength
degree of conversion of resin 35-80%
reacts with blue light at 440nm, 2mm depth cure
low weight dimethacrylates
TEGDMA - triethylene glycol dimethycrylate
added to adjust viscosity and reactivity [like paint thinner]
silane coupling agent
allows glass to preferentially bond to resin and glass rather than water [prevents water just bonding to glass filler]
depth of cure definition
the depth at which material hardness is about 80% that of the cured surface
things that can go wrong before restoration is complete
cavity preparation - caries left, unsupported enamel
bonding
contacts with teeth
placement
countering contraction stress
aesthetics
configuration factor
the ratio of bonded to unbonded surfaces
polymerisation contraction stress
pressure put on adhesive and tooth structure, can cause debonding and marginal gaps if incorrect
high polymerisation contraction stress
not good, increased stress, deformation and fracture