Alloys Flashcards
alloys
combination or mixture of two or more metals
OR
a metal with a metalloid (Si, C)
advantages of using an alloy over a metal
improved properties
higher elastic liit, fracture strength, hardness, corrosion resistamce, lower melting point
than individual metals
advantages of using an alloy over a metal
improved properties
higher elastic liit, fracture strength, hardness, corrosion resistamce, lower melting point
than individual metals
dental uses of alloys
steel [burs, insturments]
gold alloy [crown, bridge]
cobalt chrome [RPD]
amalgam [restorative]
nickell titanium [wires]
phase definition
physically distinct homogenous structure, can have more than one component
solution definition
homogenous mixture at an atomic scale
phases of grains
- metal A only =
- metal A and B in a lattice
- metal A and B in homogenous mixture, one phase
states upon crystallisation
- insoluble, 2 phases
- from intermetallic compound
- soluble and form solid solution
- substitution = atoms of one metal replace other
- interstitial = atoms markedly different in sie, smaller atoms in spaces in lattice of larger atom
difference in metal and alloy in crystallisation temps
metals - crystallise at one temperature
alloys - crystallises over temperature range
cooling and composition
must cool slowly, allows atoms to diffuse through lattice, ensure homegous grains
BUT RESULTS IN LARGE GRAINS = BAD MECHANICAL PROP, SO NO SLOW COOLING WANTED
rapid cooling of alloys
results in coring, concentration gradient is formed
coring helps improve mechanical properties by reducing dislocation movement and resulting in small grains = BETTER MECH PROP
desired speed of cooling alloys
rapid
homogenous anneal
gently vibrate and heat atoms, helps diffuse and reduce coring but not altering grains tructure, allows more homogenous proportion of metal through depth
dislocation in alloys
defect has to fall into space between large and small atoms and climb along to grain boundary
requires great deal of energy
more stress to move dislocations in solid solution, more fracture resistant and stronger than metals
eutectic alloys
when alloy melts at temperature higher than that of its individual metals [stronger together]
physically distinct grains, soluble in liwuid
cools at single temperature - not range like normal alloys