Complex ion solution colours Flashcards
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Cu2+ in aqueous solution
BLUE
Cu2+ (aq) or [Cu(H2O)6]^2+ (aq)
Fe2+ in aqueous solution
PALE GREEN
Fe2+ (aq) or [Fe(H20)6]^2+ (aq)
Fe3+ in aqueous solution
YELLOW
Fe3+ (aq) or [Fe(H20)6]^3+ (aq)
Mn2+ in aqueous solution
PALE PINK
Mn2+(aq) or [Mn(H20)6]^2+ (aq)
Cr3+ in aqueous solution
GREEN
Cr3+(aq) or [Cr(H20)6]^3+ (aq)
Adding some OH- (aq) or NH3 (aq) to aqueous solution of Cu2+
PALE BLUE PRECIPITATE
Cu(OH)2(H2O)4 (s)
Adding some OH- (aq) or NH3 (aq) to aqueous solution of Fe2+
DIRTY GREEN PRECIPITATE
Fe(OH)2(H2O)4 (s)
Adding some OH- (aq) or NH3 (aq) to aqueous solution of Fe3+
ORANGE PRECIPITATE
Fe(OH)3(H2O)3 (s)
Adding some OH- (aq) or NH3 (aq) to aqueous solution of Mn2+
PINK PRECIPITATE
Mn(OH)2(H2O)4 (s)
Adding some OH- (aq) or NH3 (aq) to aqueous solution of Cr3+
GREEN-GREY PRECIPITATE
Cr(OH)3(H2O)3 (s)
Adding excess OH- to the precipitate of Cu2+, Fe2+, Fe3+, Mn2+
NO CHANGE
(insoluble in excess NaOH )
Adding excess OH- to the precipitate of Cr3+
Cr(OH)6 ^3- (aq)
DARK GREEN SOLUTION
Adding excess NH3(aq) to the precipitate of Fe2+, Fe3+, Mn2+
NO CHANGE
Insoluble in excess NH3
Adding excess NH3(aq) to the precipitate of Cu2+
DARK BLUE SOLUTION (part ligand substitution)
[Cu(NH3)4(H2O)2]^2+ (aq)
Adding excess NH3(aq) to the precipitate of Cr3+
PURPLE SOLUTION
Cr(NH3)6^3+ (aq)