Complete synthetic routes Flashcards

1
Q

alkene to alkane conditions and reagents

A

H2 / Ni catalyst

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2
Q

alkene to alcohol conditions and reagents

A

H2O / H3PO4 catalyst

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3
Q

alcohol to alkene conditions and reagents

A

conc H2SO4 / heat

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4
Q

alkane to haloalkane conditions and reagents

A

halogen / UV

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5
Q

haloalkane to alcohol conditions and reagents

A

NaOH / reflux

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6
Q

alcohol to haloalkane conditions and reagents

A

sodium halide / H2SO4

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7
Q

haloalkane to nitrile conditions and reagents

A

NaCN / ethanol

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8
Q

haloalkane to amine conditions and reagents

A

NH3 / ethanol

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9
Q

nitrile to amine conditions, reagents and type of reaction

A

H2 / Ni / reduction

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10
Q

alcohol to ketone conditions and reagents

A

K2Cr2O7 / H2SO4 / reflux

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11
Q

ketone to alcohol conditions and reagents and type of reaction

A

NaBH4 / H2O / reduction

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12
Q

nitrile to carboxylic acid conditions and reagents and type of reaction

A

H2O / heat / HCl hydrolysis

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13
Q

hydroxynitrile to amine conditions and reagents

A

H2 / Ni

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14
Q

ketone to hydroxynitrile conditions and reagents

A

NaCN (aq) / H+

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15
Q

carboxylic acid to acyl chloride conditions and reagents

A

SOCl2

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16
Q

acyl chloride to carboxylic acid conditions and reagents

A

H2O

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17
Q

acyl chloride to primary amide conditions and reagents

18
Q

acyl chloride to secondary amide conditions and reagents

A

primary amide

19
Q

aldehyde to carboxylic acid conditions and reagents

A

K2Cr2O7 / H+ / reflux

20
Q

aldehyde to hydroxynitrile conditions and reagents

A

H2O / HCl hydrolysis / heat

21
Q

primary alcohol to carboxylic acid conditions and reagents

A

K2Cr2O7 / H+ / relfux

22
Q

primary alcohol to aldehyde conditions and reagents

A

K2Cr2O7 / H+ / distillation

23
Q

aldehyde to primary alcohol conditions and reagents

A

NaBH4 / H2O / reduction

24
Q

aldehyde to hydroxynitrile conditions and reagents

A

NaCN / H+ / nucleophilic addition

25
Q

alcohol to ester conditions and reagents and type of reaction

A

carboxylic acid / H2SO4 / estérification

26
Q

carboxylic acid to ester conditions and reagents

A

alcohol / H2SO4 / estérification

27
Q

ester to carboxylic acid conditions and reagents

A

dilute acid hydrolysis / heat

28
Q

acyl chloride to ester conditions and reagents

29
Q

ester to carboxylate conditions and reagents

A

NaOH (aq) / alkaline hydrolysis / heat

30
Q

phenol to nitro phenol reagents and type of reaction

A

HNO3 / nitration

31
Q

phenol to bromophenol reagents

32
Q

phenol to sodium phenoxide reagents

33
Q

benzene to phenyl ethanone reagents and type of reaction

A

CH3COCl
AlCl3
acylation

34
Q

phenyl ethanone to benzene (COHHCH3)
reagents and type of reaction

A

NaBH4
reduction

35
Q

benzene to methylbenzene reagents and type of reaction

A

CH3Cl
AlCl3
alkylation

36
Q

benzene to nitrobenzene reagents and type of reaction

A

HNO3
H2SO4
nitration

37
Q

nitrobenzene to aminobenzene reagents and type of reaction

A

Sn
HCl
reduction

38
Q

aminobenzene to tribromo-aminobenzene
reagents

39
Q

benzene to bromobenzene reagents and type of reaction

A

Br2
FeBr3
bromination

40
Q

benzene to chlorobenzene reagents and type of reaction

A

Cl2
AlCl3
chlorination