CL Flashcards

1
Q

Unghiul dintre valentele at de C alcani

A

109/28

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2
Q

Lungime legatura simpla C-C alcani

A

1,54

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3
Q

Reactia de halogenare alcani

A

fotochimic (lumina), 300-400 grade

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4
Q

Reactia de izomerizare alcani

A

AlCl3/AlBr3, 50-100 grade

silicati de aluminiu(zeoliti), 250-300 grade

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5
Q

Unghiuri legaturi alchene

A

120

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6
Q

Lungime legaturi duble

A

1,33

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7
Q

Aditia hidrogen alchene

A

Ni/Pt/Pd, 80-180 grade, 200 atm

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8
Q

Aditia halogeni alchene

A

solvent inert, CCl4, CH2Cl2, CS2

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9
Q

Aditia apei alchene

A

H2SO4 concentrat

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10
Q

Oxidare blanda alchene

A

KMnO4, mediu bazic

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11
Q

Oxidare energica alchene

A

KMnO4/K2Cr2O7 in mediu acid H2SO4

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12
Q

Halogenare pozitie alilica alchene

A

500-600 grade

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13
Q

Unghi legaturi alchine

A

180

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14
Q

Lungime legatura C-C alchine

A

1,204

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15
Q

Lungime legaturi C-H alchine

A

1,057

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16
Q

Hidrogenare totala alchine

A

Ni/Pt/Pd exces de H2

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17
Q

Hidrogenare partiala alchine

A

Pd/Pb 2+

18
Q

Aditia halogeni alchine

A

solvent inert

19
Q

Aditia hidracizi alchine

A

170-200 HgCl2

20
Q

Aditia apei alchine

A

H2SO4/HgSO4

21
Q

Precipitat alb galbui alchine

A

AgCCAg

22
Q

Precipitat rosu brun alchine

A

CuCCCu

23
Q

Distanta C-C vecini + C=C

A

1,39

24
Q

Unghi benzen

A

120

25
Q

Leg C-H benzen

A

1,09

26
Q

Halogenare benzen nucleu

A

FeCl3, FeBr3, AlCl3 => Cl2, Br2

HNO3 => I2

27
Q

Reactia de nitrare

A

Amestec sulfonitric => HNO3 conc si H2SO4 conc

28
Q

Reactia de sulfonare

A

H2SO4 conc / oleum

29
Q

Reactia de alchilare Friedel-Crafts

A

AlCl3 anhidra => halogenati
AlCl3 umeda => alchene
H2SO4 => alcooli

30
Q

Reactia de acilare Friedel-Crafts

A

AlCl3

31
Q

Substituenti ordinul I

A

halogenii, grupele alchil, hidroxil, amino

=> orto si para

32
Q

Subsituenti ordinul II

A

nitro, acid sulfonic, carboxil, carbonil, nitril

=> meta

33
Q

Aditia hidrogenului benzen

A

Ni, 200 grade

34
Q

Aditia hidrogen naftalina

A

Ni, Pt, Pd

35
Q

Aditia halogenilor

A

fotochimic

36
Q

Oxidarea benzenului

A

V2O5, 500C

37
Q

Oxidarea naftalinei

A

V2O5, 350 C

38
Q

Oxidarea antracenului

A

K2Cr207/ CH3-COOH

39
Q

Halogenare pozitie benzelica

A

fotochimic

40
Q

Oxidarea catena laterala (comp aromatici)

A

KMnO4/ H2SO4