CI Flashcards

1
Q

What is the equation for the iodine clock experiment?

A

H2O2 + 2H+ + 2I- –> 2H2O + I2
Colourless –> coloured
+Sodium thiosulfate and iodine

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2
Q

What is the reaction for sodium thiosulfate with iodine?

A

2S2O3 2- + I2 –> 2I- + S4O6 2-

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3
Q

What is the rate equation?

A

Rate = k[A]a[B]b
Conc = constant

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4
Q

Rate graphs/order

A

Conc/time graphs - rate/conc graphs

Straight down = straight across (0 order)
Curve down = increase proportionately (1st order)
Curve down = curve up (2nd order)

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5
Q

What is the Arrhenius equation?

A

k = Ae ^ (-Ea/RT)
A = arrhenius constant
e = exponential

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6
Q

What happens to Ea/k as temp increases?

A

Smaller
K increases

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7
Q

Arrhenius equation with removed exponential

A

ln k = ln A - Ea/RT

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8
Q

What does a graph of ln k against 1/T tell us?

A

Gradient = -Ea/R

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9
Q

Arrhenius in the form y = mx + c

A

lnk = -Ea/RT + ln A

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10
Q

How to find A from ln A

A

e ^ ln A

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11
Q

What is the rate determining step?

A

Slowest step in multi-step reaction
Multi-step can be sped up by adding catalyst/increasing step

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12
Q

N2O systematic name

A

Nitrous oxide

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13
Q

NO systematic name

A

Nitric oxide

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14
Q

Test for nitrate ions

A

Heat with Devarda’s alloy to form ammonia gas
Ssmelly + bleaches

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15
Q

How to measure initial rate using half life graph

A

Slope/gradient of tangent at origin

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16
Q

What is the difference between by-product and co-product?

A

By = side reaction
Co = main reaction

17
Q

How do you remove methane from methanol?

A

Condense it out