chemsitry tests Flashcards
Soluble salts
- Ammonium, sodium, and potassium salts
- Nitrate salts
- Nearly all chloride, bromide, and iodide salts
- Nearly all sulfates
- Ammonium, sodium, potassium carbonate salts
- Ammonium, sodium, potassium hydroxide salts
Insoluble salts
- Silver chloride, silver bromide, silver iodide, lead chloride
- Barium sulfate, calcium sulfate, lead sulfate
- Most carbonates
- Most hydroxides
Testing for cations using aqueous sodium hydroxide
Ammonium
Ammonia gas produced on heating - turns red litmus paper blue
Testing for cations using aqueous sodium hydroxide
Calcium
White percipitate, insoluble in excess
Testing for cations using aqueous sodium hydroxide
Copper(II)
Light blue percipitate, insoluble in excess
Testing for cations using aqueous sodium hydroxide
Iron (II)
Green percipitate, insoluble in excess
Testing for cations using aqueous sodium hydroxide
Iron (III)
Red-brown percipitate, insoluble in excess
Testing for cations using aqueous sodium hydroxide
Zinc (II)
White percipitate, soluble in excess, gives a colourless solution
Testing for cations using aqueous ammonia
Calcium
No percipitate, very slifhrly white percipate
Testing for cations using aqueous ammonia
Copper (II)
Light blue percipitate, soluble in excess, dark blue solution
Testing for cations using aqueous ammonia
Iron (II)
Green percipitate, insoluble in excess
Testing for cations using aqueous ammonia
Iron (III)
Red-brown percipitate, insoluble in excess
Testing for cations using aqueous ammonia
Zinc (II)
White percipitate, insoluble in excess, gives colourless solution
Flame test
Lithium
Red
Flame test
Sodium
Yellow
Flame test
Potassium
Lilac
Flame test
Copper (II)
Blue-green
Testing for anions
Carbonate
Test: Dilute acid
Result: Effervesence, carbon dioxide produced
Testing for anions
Chloride (in solution)
Test: Acidify with dilute nitric acid, then add aqeous silver nitrate
Result: White percipitate
Testing for anions
Bromide (in solution)
Test: Acidify with dilute nitric acid, then add aqeous silver nitrate
Result: Cream percipitate
Testing for anions
Nitrate (in solution)
Test: Add aqueous sodium hydroxide then aluminium foil; warm carefully
Result: Ammonia gas produced
Testing for anions
Sulfate (in solution)
Test: Acidift then add aqueous barium nitrate or barium chloride
Result: White percipitate
Fuels
Small number of carbon atoms
- Low boiling points
- Evaporate and rise up first
Fuels
Higher number of carbon
- Higher boiling point
- ## As they evaporate, they condense at a higher temperature - lower down the tower
Fuels
Refinery gas
- Used for bottled gas for cooking
- 1-4 Carbon atoms
- Boiling point of under 40 degrees
- Gases at low temperatures
- Very low viscosity (flows easily)
Fuels
Gasoline
- Used in cars
- 5 - 6 Carbon atoms
- Boiling point of 40-100
- Very volatile
- Very low viscosity
Fuels
Naphtha
- Feedstock for making chemicals
- 5 - 9 Carbon atoms
- Boiling point of 60-100
- Volatile
- Low viscosity
Fuels
Diesel oil/gas
- Fuel in diesel engines
- 13-25 Carbon atoms
- Boiling point: 250 - 350
- Low volatility
- High viscosity
Fuels
Bitumen
- Used for road surfaces
- Carbon atoms of over 40
- Boiling point over 500
- Very low volatility
- High viscosity
Alkane general formula
CnH2n+2
Alkene general formula
CnH2n
Alkanes
- Unreactive because C-H bonds are strong
- Can be used as fuel because they combust
- Saturated hydrocarbons (each molecule only has single covalent bonds)
- Every atom has a full outer shell
Alkenes
Thermal cracking
- Cracking long chain alkanes into smaller ones
- High temperature (800 degrees)
- Ethene and hydrogen gas produced
Catalytic cracking
- Another form of cracking
- Uses aluminium and ceramic based catalysts that lower the temperature required to 500 degrees
- Cheaper
- Thermal cracking more useful fo rlonger chain hydrogcarbons
Detecting alkenes
- Bromine
- Hydrogen
- Steam
- Confirm the presence of a double bond by testing the ability of an alkene to undergo additionr Reactions
Detecting alkenes
Bromine
- Alkenes react with halogens such as bromine
- Brown to colourless
Detecting alkenes
Hydrogen
- Temperature of 200 degrees
- Presence of a nickel catalyst
- Also called hydrogenation
Detecting alkenes
Steam
- 300 degrees
- Presence of steam and phoshoric acid, which acts as a catalyst to produce alcohol
- Water splits into an H atom and an OH group
Hydration of ethene
- ## Synthetic ethanol
Molten lead bromide
Product at cathode: Lead
Product at anode: Bromide
Observations: Silvery solid at the cathode, brown gas at the anode
Concentrated aqueous sodium chloride
Product at cathode: Hydrogen
Product at anode: Chloride
Observations: Colourless gas at the cathode, pale yellow green gas at the anode which bleaches damp litmus paper
Acid + metal
Observation:
* Effervescence
* Heat evolved
* Hydrogen gas formed
Reaction occurring:
Acid + Metal -> Salt + Hydrogen
Acid + Base
Observation:
Indicator goes green
Reaction occurring:
Neutralisation
Acid + Base -> Salt + Water
Bronze
Copper and tin
Mild steel
Iron and about 0.25% carbon
High carbon steel
Iron and up to 2.5% carbon
Brass
Copper and zinc
Stainless steel
Iron, carbon, chromium and nickel