Chemistry Video 3 Flashcards
Atomic Theory
John Dalton, 1807
- Matter consists of tiny particles called atoms, which are the smallest indivisible unit of a particular element
- An element consists of only one type of atom, which has a particular mass characteristic of that element
- Atoms of a given element are different from atoms of any other element
- A compound consists of atoms of 2 or more elements combined in whole number ratios, and that ratio is constant for that compound
- When a chemical change occurs, atoms are neither created nor destroyed, they simply rearrange to form different combinations
Law of definite proportions/Law of constant composition
Any sample of a compound contains the same ratio of elements by mass
Law of multiple proportions
When 2 elements react with one another, the second element can react in small whole number ratios
Cathode Ray Tube
1897, JJ Thompson. Used cathode ray tubes, which are tubes containing metal electrodes in a vacuum. When a voltage was applied, a cathode ray beam appeared between the electrodes. The cathode ray beam bends towards the positively charged plate. This indicated that inside an atom, there must be negatively charged particles. Thompson used the angle of the beam and the power of the magnetic field to calculate the charge to mass ratio of the electron and discovered that electrons are lighter than atoms. He concluded that electrons are inside atoms
Oil Drop Experiment
1909, Robert Millikan. Movement of microscopic oil droplets were studied to determine the magnitude of the charge of an electron, and therefore the electron’s mass.
Plum pudding model
Thompson; electrons sit amongst positively charged matter
Gold Foil experiment
Ernest Rutherford, 1909. Fired alpha particles (tiny positively charged particles) at a thin piece of gold. Most particles went through the gold foil to the detector on the opposite side, but 1 in 8000 particles were deflected at some angle with high energy. Concluded that the atom is mainly empty space and that all the positive charge must be concentrated in a tiny dense nucleus at the centre of the atom
Subatomic particles, mass, charge
Protons (1.6710^(-24)g, +1.60210^(-19)C); electrons (9.1210^(-28)g, -1.60210^(-19)C); neutrons (1.67*10^(-24)g, no charge)
Atom’s mass number
Protons + neutrons; each nucleon = 1 atomic mass unit (amu); neutrons in nucleus can vary
Isotope
Atoms of a given element with different numbers of neutrons
Atomic number
Number of protons in an atom
Electric charge of an atom
Number of protons - number of electrons
Nuclide symbol
Chemical symbol for the element in the centre, atomic number in the subscript to the left, mass number in superscript to the left, charge in superscript to the right
Isotopes of hydrogen
Hydrogen-1 (0 neutrons) called protium, Hydrogen-2 (1 neutron) called deuterium, Hydrogen-3 (2 neutrons) called tritium. Not found in equal abundance, have different stabilities. Most hydrogen is hydrogen-1
Isotopes of carbon
Carbon-12 (6 neutrons), Carbon-13 (7 neutrons), Carbon-14 (8 neutrons). Most carbon is carbon-12
Atomic mass
Have decimal places. Average mass of an atom of a particular element, taking in to account the relative abundance of all the isotopes of the specific element. Atomic mass is determined by multiplying each mass number of an isotope by its relative abundance, and then add them. Units are amu.
Monoatomic ion
Singular atom with a formal charge
Polyatomic ion
Molecule with a formal charge
Ionic compound
Formed by cations and anions being attracted to each other. Cation + Anion; Monoatomic metal cation + Polyatomic anion
Neutral compound
Formed when metals and nonmetals come together in a specific ratio. The amount of positive and negative charge must cancel out
Ammonium ion
NH4(+)
Acetate ion
C2H3O2(-)
Carbonate ion
CO3(2-)