Chemistry of the Atmosphere Flashcards

1
Q

what is the percentage composition of the atmosphere?

A
  • 78% nitrogen
  • 21% oxygen
  • 1% all other gases incl. water vapour and CO2 (0.03%)
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2
Q

what was the atmosphere like 4.6 billion years ago?

A
  • massive amounts of volcanic activity helped the earth cool down more quickly by releasing heat energy
  • large amounts of CO2 released, as a consequence, along with water vapour - but the earth’s surface was still too hot for the water vapour to condense onto - at this time the atmosphere was ~90% CO2
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3
Q

what was the atmosphere like 3.4 billion years ago?

A
  • the earth’s surface became cool enough for water to condense onto it, allowing lakes, rivers and oceans to develop
  • CO2 dissolved into the developing oceans, enabling the amount of CO2 in the atmosphere to decrease
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4
Q

what was the atmosphere like 2.7 billion years ago?

A
  • plants and algae photosynthesised, decreasing CO2 and increasing O2 levels
  • O2 reacted in the atmosphere to produce ozone (O3) providing a protective layer of gas around the outer limits of the atmosphere, protecting life on earth from UV radiation
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5
Q

what was the atmosphere like 200 million years ago?

A
  • oxygen rich, CO2 poor
  • Nitrogen levels in the atmosphere begin to increase as denitrifying bacteria in soil break down compounds containing nitrogen
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6
Q

describe 5 ways in which today’s atmosphere is different from that of the Earth 4.6 billion years ago

A
  • Higher oxygen levels
  • higher nitrogen levels
  • lower co2 levels
  • less water vapour
  • less hydrogen
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7
Q

describe the 4 key events that scientists theorise have changed the composition of the Earth’s atmosphere, from what is was 4.6 billion years ago to what it is today

A
  • earth’s surface cooled enough for water vapour to condense on it
  • CO2 dissolved in newly formed oceans and rivers
  • plants and algae that photosynthesise began to evolve, increasing O2 and decreasing CO2 levels
  • denitrifying bacteria began to break down nitrogen-containing compounds
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8
Q

what were the factors that reduced atmospheric carbon dioxide levels?

A
  • formation of the oceans
  • photosynthetic organisms evolved
  • evolution of marine animals
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9
Q

how is human activity causing CO2 levels to rise?

A
  • by unlocking carbon dioxide that has been locked up in fossil fuels and sedimentary rocks
  • deforestation
  • cattle farming
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10
Q

how is carbon dioxide unlocked from fossil fuels and sedimentary rocks?

A
  • burning fossil fuels releases locked-up CO2 and energy - CH4 + O2 ⇒ CO2 +H2O
  • thermal decomposition of limestone to produce cement and concrete released locked-up CO2 - CaCO3 ⇒ CaO + CO2
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11
Q

how do greenhouse gases cause global warming?

A
  • UV radiation with a short wavelength comes from the sun and hits the earth’s surface
  • it reflects as longer wavelength infra-red radiation but can’t get through the greenhouse gases, so the heat gets trapped
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11
Q

how do greenhouse gases help to support life on earth?

A

stop infra-red radiation passing out of the atmosphere and trapping heat which maintains a suitable temperature for life to thrive.

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12
Q

give two potential consequences of rising sea levels

A

Increased flooding and loss of coastal habitats/coastal erosion

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13
Q

give some potential consequences of climate change

A

Rising sea levels, extreme weather events, loss of biodiversity, crop failure and famine, drought

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14
Q

name 5 atmospheric pollutants from burning fossil fuels

A
  • Carbon monoxide
  • sulfur dioxide
  • nitrogen oxides (NOx gases)
  • carbon particulates
  • carbon dioxide
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15
Q

what are NOx gases caused by?

A

oxygen and nitrogen in the atmosphere reacting in very hot engines

16
Q

why are NOx gases bad?

A

they cause acid rain

17
Q

what is a remedy for NOx gases in the atmosphere?

A

use a catalytic converter to convert NOx gases back into nitrogen and oxygen

18
Q

what is sulfur dioxide in the atmosphere caused by?

A

Burning of fossil fuels containing sulfur, which reacts with oxygen

19
Q

why is sulfur dioxide in the atmosphere bad?

A

it causes acid rain

20
Q

what is a remedy for sulfur dioxide in the atmosphere?

A

remove sulfur from fuel and use FGD (flue-gas desulfurization)

21
Q

what are carbon particulates in the atmosphere caused by?

A

Incomplete combustion of fuels, creating smoke

22
Q

why are carbon particulates in the atmosphere bad?

A

create smog and poor air quality in turn, causing respiratory problems

23
Q

what is a remedy for carbon particulates in the atmosphere?

A

Using filters in industrial processes to capture carbon particulates or do complete combustion by providing more oxygen

24
what is carbon monoxide in the atmosphere caused by?
Incomplete combustion of fossil fuels
25
why is carbon monoxide in the atmosphere bad?
it is toxic
26
what is a remedy for carbon monoxide in the atmosphere?
use more oxygen to complete combustion
27
what is carbon dioxide in the atmosphere caused by?
burning fossil fuels
28
why is carbon dioxide in the atmosphere bad?
is a greenhouse gas so contributes to global warming
29
what is a remedy for carbon dioxide in the atmosphere?
- Carbon capture and storage (CCS) technology - stop burning so many fossil fuels (burn alternative fuels - use things requiring less energy - use green energy
30
name 4 greenhouse gases
- carbon dioxide - carbon monoxide - sulfur dioxide - methane
31
identify a natural and man-made source for the following GHG: methane, CO2, water vapour
- methane: cows and landfill sites - CO2: combustion of fossil fuels and volcanoes - water vapour: combustion of fossil fuels and volcanoes
32
what is a caron footprint?
the total amount of emitted CO2 and other greenhouse gases over the lifecycle of a product, service, or event
33
what are some ways companies/industry can reduce their carbon footprint?
- tax companies based on the size of their carbon footprint - enforce companies to display their carbon footprint for their product/service - produce carbon footprint limits for companies and fine them if they exceed their cap - businesses should be forced to include carbon capture into their business plant - allow tax reductions for companies that utilise carbon capture in their business
34
what are some ways individuals can reduce their carbon footprint?
- use locally sourced goods - use public transport or walk - turn lights and electrical appliances off when not in use - leaving equipment in standby still uses electrical energy - eat less red meat, as the carbon footprint for beef and lamb far exceeds that for other meats - fly less - use more energy efficient devices
35
what are the 6 R's in reducing carbon footprint?
- Recycle: reusing materials to make something out of them - Re-use: reusing the same product again - Reduce: buy less - Repair: fix things instead of buying new ones - Refuse: if it isn't necessary, don't buy it - Re-think: how we buy things
36
what are some ways governments can reduce their carbon footprint?
- governments should have national quotas for greenhouse gas emissions - ban international markets that allow governments to trade quotas for greenhouse gas emissions
37
what are some problems when trying to reduce carbon footprint?
- general public may not be aware of what they can do to reduce their carbon footprint or that they have one ⇒ the public needs educating about the environment consequences of their carbon footprint - economic consideration: it may be expensive to change a lifestyle to one with a lower carbon footprint (ie heat pumps replacing traditional central heating boilers) - general public can become confused by scientists disagreeing about the causes and consequences of climate change
38
What reasons might people have to play down the contribution of greenhouse gas emissions to climate change?
- A common bias is that an individual is involved in an industry which relies on, for example, burning fossil fuels. - Burning fossil fuels is central to this individual's profession but it is also known to release lots of carbon dioxide, which is a greenhouse gas. - Therefore, it is in the individual's interest to play down the negative effects of greenhouse gases in order to avoid more regulation of the relevant industry.