CHEMISTRY FOR ENGINEERS MIDTERM EXAMS Flashcards
substances that assume regular, repeating patterns of arrangement of their atoms. substances condense into crystals as solids that fill space as completely as possible.
crystals
can be thought of as spheres, and how they fill up a theoretical cubical box called a unit cell.
atoms
the seven crystal structures
simple cubic, face-centered cubic, body-centered cubic, hexagonal closed pack, orthorhombic, rhombohedral, tetragonal, and monoclinic
made up of atoms at each corner of a cube, and is envisioned as eight spheres on eight corners of a cube. this structure has equal sides, with all the angles of each side as 90.
this is a rare structure and the only elements that occur in this structure are oxygen, fluorine and polonium.
simple cubic
crystal system is more common. it is made up of atoms at each corner of a cube with atoms on each “face”
many elements occur as this crystal system in their solid states like aluminum, silver, copper, gold, and nickel. gases in family 8A.
face-centered cubic
made up of atoms at each corner of a cube but has an atom at the center.
the alkali metals in group 1A and barium and radium from group IIA are some of the elements
body-centered cubic
atoms are piled as layers of hexagons with one atom on each corner and a center atom on the hexagon. the next layer of atoms fill the spaces in between the atoms of the first layer, hence, closed packed.
titanium, zinc, magnesium, and cadmium, including helium and hydrogen gases.
Hexagonal closed packed
orthorhombic crystals or rhombic system
consists of three equal angles of 90 degrees. the sides are of different lengths. four types of unit cells, primitive, face-centered, body-centered, and side centered.
sulphur, chlorine, bromine, iodine, protactinium, and neptunium.
its axes (a, b, c) are all equal. its corner angles are equal, and all are not perpendicular.
mercury, antimony, and bismuth
rhombohedral or trigonal system
three corner angles are perpendicular and two of its sides are of equal length, with the third side either longer or shorter than the other two.
indium and tin
tetragonal
three unequal sides comprise it. sides a and c are inclined toward each other at an oblique angle, while the third side b is perpendicular to a and c. two angles are perpendicular while the third angle is not.
curium, berkelium, californium, einsteinium, fermium, mendelevium, nobelium, and lawrencium
monoclinic
elements that generally are that are shiny, good conductors of heat and electricity, ductile and malleable. they have the ability to conduct heat and electricity due to the closely packed arrangement of their atoms, making it easier for each atom to transfer with each other.
metals
property of metals to be pulled into wires, while malleability is the property of metals to be formed into sheets. it is because of these properties that metals and their alloys can be formed into different shapes such as pipes, tubes, or bars.
ductility
the row in a periodic table, elements in the same period are same in size.
period (or series)
the column in a periodic table, elements in the same group have the same chemical and electronic properties
group (or family)