Chemistry (Chapter 8) Flashcards

1
Q

What is a covalent bond?

A

A bond formed by the sharing of electrons between atoms.

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2
Q

What is a molecule?

A

A neutral group of atoms joined together by covalent bonds.

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3
Q

What is a diatomic molecule?

A

A molecule consisting of two atoms.

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4
Q

What is a molecular compound?

A

A compound that is composed of molecules.

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5
Q

What is a molecular formula?

A

A chemical formula of a compound that shows the kinds and number of atoms present in a molecule of a compound.

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6
Q

What is a single covalent bond?

A

A bond formed when two atoms share a pair of electrons.

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7
Q

What is a structural formula?

A

A chemical formula that shows the arrangement of atoms in a molecule or a poly-atomic ion; each ash between a pair of atoms indicates a pair of shared electrons.

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8
Q

What is an unshared pair?

A

A pair of valence electrons that is not shared between atoms.

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9
Q

What is a double covalent bond?

A

A bond in which two atoms share two pairs of electrons.

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10
Q

What is a triple covalent bond?

A

A covalent bond in which three pairs of electrons are shared by two atoms.

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11
Q

What is a coordinate covalent bond?

A

A covalent bond in which one atom contributes both bonding elements.

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12
Q

What is a polyatomic ion?

A

A tightly bound group of atoms that behaves as a unit and has a positive or negative change.

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13
Q

What is bond dissociation energy?

A

The energy that is required to break the bond between two covalently bonded atoms; this value is usually expressed in kJ per mol of substance.

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14
Q

What is resonance structure?

A

One of the two or more equally valid electron dot structures of a molecule or polyatomic ion.

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15
Q

What is a molecular orbital?

A

An orbital that applies to the entire molecule.

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16
Q

What is a bonding orbital?

A

A molecule orbital that can be occupied by two electrons of a covalent bond.

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17
Q

What is a sigma bond?

A

A bond formed when two atomic orbitals combine to form a molecular orbital that is symmetrical around that axis connecting the two atomic nuclei.

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18
Q

What is a Pi bond?

A

A covalent bond in which the bonding electrons are most likely to be found in sausage-shaped regions above and below the bond axis of the bonded atoms.

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19
Q

What is a tetrahedral angle?

A

A bond angle of 109.5 that results when a central atom forms four bonds directed toward the center of a regular tetrahedron.

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20
Q

What is the VESPR theory?

A

Valence-shell electron-pair repulsion theory; because electron pairs repel. molecule adjust their shapes so that the valence electron pairs are as far apart as possible.

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21
Q

What is hybridization?

A

The mixing of several atomic orbitals to form the same total number of equivalent hybrid orbitals.

22
Q

What are the VSEPR model and shapes?

A
  1. Linear
  2. Trigonal planar
  3. Bent
  4. Pyramidal
  5. Tetrahedral
23
Q

What are the van der Waals forces?

A

The two weakest intermolecular attractions-dispersion interactions and dipole forces.

24
Q

What is an unshared pair?

A

A pair of valence electrons that is not shared between atoms.

25
How many neighbors does a hexagonal close-packed arrangement have?
Twelve.
26
Molecules consisting of two atoms.
Diatomic molecules.
27
The chemical formula of a molecular compound?
Molecular formula.
28
Do molecular compounds have high or low melting points?
Low
29
Joins atoms held together by sharing electrons?
Covalent bonds.
30
Two atoms held together by sharing one pair of electrons are joined by what?
Single covalent bond.
31
Represents the covalent bonds as dashes and shows the arrangement of covalently bonded atoms.
Structural formula.
32
Pair of valence electrons that is not shared between atoms.
Unshared pair.
33
Bond that involves two pairs of shared pairs of electrons.
Double covalent bonds.
34
Bonds that involves three shared pairs of electrons?
Triple covalent bond.
35
A covalent bond in which one atom contribute both bonding electrons.
Coordinate covalent bond.
36
A tightly bound group of atoms that has a positive or negative charge and behaves as a unit?
Polyatomic unit.
37
The energy required to break the bond between two covalently bonded atoms?
Bond dissociation energy.
38
Structures that occur when it is possible to draw two or more valid electron dot structures that have the same number of electron pairs for a molecule?
Resonance structures.
39
What are three ways the octet rule can sometimes fail to be obeyed?
When the total number of valence electrons is an odd number, when molecules have less than a complete octet of electrons, when molecules have more than a complete octet of electrons.
40
The quantum mechanical model of bonding assumes that atomic orbitals overlap to produce ______.
Molecular orbitals.
41
A molecular orbital that can be occupied by two electrons of a covalent bond?
Bonding orbital.
42
Produced when two atomic orbitals combine to form a molecular orbital that is symmetrical around the axis connecting two atomic nuclei.
Sigma.
43
Produced when atomic orbitals overlap side by side?
Pi bond.
44
What states that because the electron pairs repel, molecular shape adjusts so the valence-electron pairs are as far apart as possible?
VSEPR theory.
45
The weakest of all molecular interactions, are caused by the motion of electrons.
Dispersion forces.
46
Arrange the following in: order of increasing strength: dipole interactions, dispersion interactions, and hydrogen bonds.
Dispersions dipole hydrogen
47
A substance in which all of the atoms are covalently bonded to each other.
Network solid.
48
A term used to describe the weakest intermolecular attractions; these include dispersion forces and dipole forces
Van der Waals forces.
49
A molecular in which one end is slightly positive and the other end is slightly negative.
Polar molecule
50
Bond in which a hydrogen covalently bonded to very electronegative atom is also weakly bonded to an unshared electron pair of another electronegative atoms.
Hydrogen bond.
51
A molecule in which one end is slightly positive and the other end is slightly negative.
Polar molecule