Chemistry Chapter 5: Phases, Gases and Solutions Flashcards
Why would HF have a small effect on the boiling point of water compared to HI, HCl and HBr
The boiling point of a solution depends on the number of particles of solute present in solution.
Hydrochloric acid hydrobromic acid hydroidic acid are strong acids
HF is weak and doesn’t completely dissociate
When each acid breaks down, it dissociates into 2 moles of ions per mole of solute dissolved particles from HF
Therefore, there are fewer fewer dissolved HF ions in solution compared to strong acids like HCl, HBr, and HI.
A colligative property is a property that is dependent on the
ratio of solute to solvent concentration, but not the identity of the solute (or the solvent).
How does polarity, molecular weight affect osmosis
Polarity and molecular weight don’t affect osmosis
Supersaturation
a state where a solution contains more of the dissolved material than could be dissolved by the solvent under normal circumstances. If a supersaturated system is perturbed, the excess solute will crystallize (i.e. precipitate) out of solution and onto the glass rod
At STP, one mole of an ideal gas occupies a volume
22.4L
Charles Law
Boyles Law
Avogardo’s Law
Combined Law
If the total pressure for the products of this reaction is 1.2torr, how do you find the partial pressure of H2O?
1) find total number of mols of products (in this case there are 3 mols)
2) find proportion of species in question (in this case 2 H2O mols out of 3 total mols)
3) (2/3)*1.2 = 0.8 torr pH2O
If you see a thermal expansion coefficient given in a table, check if they are asking about volume change—
Make sure to multiply by 3!!!
Henry’s Law
Henry’s law, statement that the weight of a gas dissolved by a liquid is proportional to the pressure of the gas upon the liquid
High osmolarity means what?
High concentration of solutes. Therefore, answer is B because the body is trying to converse water. the urine is highly concentrated, meaning very salty because water is being retained
osmolarity vs concentration
Summary: Osmolarity measures the total number of osmotically active particles per liter of solution, while concentration measures the moles of solute per liter, differing when solutes dissociate.
Example: A 1 M NaCl solution has an osmolarity of 2 Osm/L because NaCl dissociates into Na⁺ and Cl⁻ ions.