Chemistry and Maths Flashcards
What is hydrolysis?
What is condensation?
A chemical reaction or process in which a chemical compound is broken down by reaction with water.
A reaction where two molecular fragments are joined and water is produced.
What is a hydrogen bond?
A special type of dipole-dipole bond that exists between an electronegative atom and a hydrogen atom bonded to another electronegative atom.
What are the atoms that can form hydrogen bonds?
Oxygen, Nitrogen, Sulphur, and Phospahte.
What does: -Polar -Non-polar -Amphiapathic Mean?
Polar molecules dissolve in water.
Non-Polar molecules don’t dissolve in water.
Amphiapathic molecules are part polar, part non-polar.
What does electronegative mean?
The power of an atom or nucleus to withdraw or attract electrons in a covalent bond.
Where is the carbonyl group in a aldehyde and a ketone?
Aldehyde - end of carbon skeleton
Ketone - attached to two other carbons
What does ionised mean?
When an atoms has had one or more electrons removed
How do you calculate pH?
pH = -log[H+]
What is the Henderson-Hasselbalch equation?
pH = pKa + log[base]/[acid]
The smaller the pKa value…..
…..the stronger the acid.
What pH range do buffers work at best?
Numbers near their pKa value
What are two examples of biological buffers in the body?
Dihydrogen phosphate system and carbonic acid system
What is the only amino acid whose side chain has a pKa close to neutrality?
Histidine
What is a calorie?
The amount of energy required to increase the temperature of one gram of water by 1 degree.
(Not to be mixed up with the nutritional Calorie).
What is bond energy?
Energy required to break a bond, energy released when a bond is formed.
What is the activation energy?
Amount of energy required for a reaction to occur.
What is Gibbs free energy? What is it represented by?
What is the equation for Gibbs free energy?
What do each of the symbols mean?
The amount of energy in a system available to do work. DeltaG.
DeltaG = DeltaH - TDeltaS
Delta H = change in enthalpy
T = temperature (K)
DeltaS = entropy
What is enthalpy?
What is enthalpy change?
What does a positive enthalpy change mean?
What does a negative enthalpy change mean?
Internal energy (heat) of a system
Heat change at constant pressure.
Endothermic (requires heat)
Exothermic (releases heat)
What is entropy?
What does a positive entropy signify?
Measure of disorder
Increased randomness, increased likelihood of a reaction
Do strong acids dissociate in water?
Do weak acids dissociate in water?
Yes completely
Yes but not completely
What is kinetics the study of?
The rate at which chemical reactions occur
What is Avrogados number?
6.022x10 to the power of 23
What is a nucleophile?
They are electron rich and are attracted to positively charged groups
What are electrophiles?
Species that are attracted to negative centers