Chemistry (Acids and Bases) Flashcards
Solute and Solvent
Solute dissolved + phase change
Solvent in greater amount
Solubility Factors
Measure of how much something dissolves
- Solute in liquid or liquid in liquid. Temp inc.= Solubility inc.
- Gas in liquid. Temp inc. Solubility dec.
- Polarity: polar dissolves polar and non-polar dissolves non-polar
- Size: Size inc. solubility dec.
Precipitation
Add too much compound and hits solubility limit/saturation
- solute drops out of solution.
- liquid-liquid undergo phase split => 2 liquid phases with least dense on top.
Units of concentration
Percentage composition: mass of x/ total mass or moles of x/total moles
Molarity: moles of solute / liters of solution.
Molality: moles of solute/ kg of solvent.
Normality: Equivalents of X/ liters of solution.
Mole fraction
Moles/ total moles
Oxidation numbers
- Pure elements =0
e. g Zn, O₂, F₂
Ions Zn ²+—> +2 Fe ³+—> +2 Hg₂ ²+—> +1 for each Hg atom O ₂ ²- (peroxide)—> -1 O ₂ ¹-
Compounds
F=-1
O=-2
H is +1 with nonmetal and -1 with metal.
Examples
MgCl ₂= +2 + 2(-1)= 0
AlF ₃= +3 + 3(-1)= 0
SO4 ²- = 6 + 4(-2) = 2-
Dilutions
Calculating # of moles in a system and divide by total volume.
M1V1=M2V2
Solubility product Ksp
- Extent to which a solid dissolves.
- Will only be used for salts with a low solubility.
Ksp= [Products] => concentrations of the ions that are formed when the solid dissociates
Common Ion Effect and Molar solubility
What if there is already common ion present between the solute added and substance already dissolved in the water—> common ion effect
Molar solubility: amount of solute required to reach saturation.
Ksp and Qsp
Ksp > Qsp: unsaturated (no precipitate)
Ksp = Qsp: equilibrium ( no precipitate)
Ksp< Qsp: past saturation (precipitate will form until equilibrium)
Lewis, Bronsted-Lowry, and Arrhenius
Bronsted-Lowry Acid: proton donor
Bronsted-Lowry Base: proton acceptor
Arrhenius Acid: Release H+ in solution
Arrhenius Base: Release OH- in solution
Lewis Acid: Electron pair acceptor
Lewis Base: Electron pair donor
Titrations
Finding concentration of unknown substance