chemistry Flashcards
Haber process
Ammonia is made and its t’s an exothermic reaction, which means it gives off heat. 5 steps
1.) H2 is obtained from methane
N2 is obtained from the air
They are pumped into the compressor through a pipe
2.) Inside the compressor, the gases are compressed to around 20 000 killopascals
3.) The gases are put under high pressure and pumped into a tank with layers of iron catalyst, heated to 450 °C. In the tank, some of the nitrogen and hydrogen react to make ammonia
- N₂ (g) + 3H₂ (g) ⇌ 2NH₃ (g)
4.) The unreacted hydrogen and nitrogen, along with the ammonia, move into a cooling tank. where the ammonia turns into a liquid and is taken out and stored in containers.
5.) The unreacted H2 and N2 gases are recycled back into the system and start over again
Air in atmosphere
- 78% nitrogen
- 21% oxygen
- 0.04% carbon dioxide
Diatomic atom
Molecules made of 2 atoms
Alkenes
- are unsaturated (double bond) with carbon double bonds C=C
-Covalent bond (Atoms bond to hare electrons) - general general formula is CnH2n, 2*n, n = number of carbons, to find number of hydrogen
-more reactive than alkanes
Manufactre of alkenes
*Catalytic Cracking
- Converts long-chain hydrocarbons into shorter chains
- used to make Used to make polymers (plastics)
- Hydrogen used to make ammonia
- Kerosene and diesel oil are used to cracking to produce petrol, other alkenes, and hydrogen
how to tell from Alkenes to Alkanes
- Use Bromine water (an orange colored soltion)
- When bromine water is with an alkane, the solution remains orange
- When bromine water is with an alkene, the solution will go colourless
Alkanes
- Are unsaturated (single bond) with carbon double bonds C-C
-Covalent bond (Atoms bond to share electrons)
-Consists of non-metal atoms - The general formula of the alkanes is CnH2n+2 (use 2*n+2 , N = number of carbons to find number of hydrogen)
-are colourless compounds - undergo combustion (a chemical reaction with oxygen that releases heat and light)
- Alkanes undergo complete combustion
Form:
Alkane + oxygen → carbon dioxide + water - React with halogens in the presence of light in substitution reactions (replace an atom molecule)
Avogadro Constant
6.02x10^23
- number of particles in one mole
- mass of 1 mole of a substance is known as the molar mass
-For an element, the relative atomic mass written in grams (g)
Avogadro Law:
* If you have the same temperature and pressure, then equal numbers of gas particles (moles) will always take up the same amount of space
- At room temperature and pressure, the volume by one mole (molar volume) of any gas was found to be 24 dm^3/ 24,000 cm^3
-Volume of gas = Moles x Molar Volume
-Number of moles of a gas = Volume ÷ Molar Volume
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Ionic bond/ ion
Ionic bond:
* the electrostatic attraction between positively charged ions (cations) and negatively charged ions (anions), formed when electrons are transferred from a metal to a non-metal.
- ion: an electrically charged atom/group of atoms formed by the loss/gain of electrons
- Negative ions are called anions and form when atoms gain electrons, meaning they have more electrons than protons
- Positive ions are called cations and form when atoms lose electrons, meaning they have more protons than electrons
-Elements in Group 1 form ions with a 1+ charge
-Elements in Group 2 form ions with a 2+ charge
-Elements in Group 6 form ions with a 2- charge
- Elements in Group 7 form ions with a 1- charge
Electrolysis
- Electrolysis is a process where an electric current is used to break down a molten (liquid) ionic compound into its elements
- The process also occurs for aqueous solutions of ionic compounds
- An Electrode is a rod (usually metal or graphite) that conducts electricity into or out of an electrolyte
- Anode is the positive electrode of an electrolysis cell
- An anion is a negatively charged ion that is attracted to the anode
- A cathode is the negative electrode of an electrolysis cell
- A cation is a positively charged ion that is attracted to the cathode
- Metals and hydrogen form
- Metals and hydrogen form positive ions, either form metal/ hydrogen gas (formed at the cathode)
- If the metal is less reactive than hydrogen, then the metal is produced
- If the metal is more reactive than hydrogen, then hydrogen gas is produced instead
- Non-metals form negative ions, so non-metals are formed at the anode (execpt hydrogen)
- The power supply provides the cathode with a supply of electrons, causing it to become negatively charged
Positive ions (cations) in the electrolyte move towards the cathode where they gain electrons - Negative ions (anions) in the electrolyte move towards the anode where they lose electrons
- The electrons move from the anode back towards the power supply
Ionic half equation
- Oxidation: the loss of electrons
- Reduction: the gain of electrons
- As the ions come into contact with the electrode:
- Ions are charged particles (either positive or negative).
- When ions gain or lose electrons, they become neutral atoms or molecules.
- At the anode, negatively charged ions lose electrons
So, oxidation occurs at the anode - At the cathode, the positively charged ions gain electrons
So, reduction occurs at the cathode