Chemistry Flashcards
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1
Q
E - 2, LP - 0
A
Linear
2
Q
E - 3, LP - 0
A
Trigonal Planar
3
Q
E - 3, LP - 1
A
Bent
4
Q
E - 4, LP - 0
A
Tetrahedral
5
Q
E 4 LP 1
A
Trigonal Pyramid
6
Q
E 4 LP 2
A
Bent
7
Q
E 5 LP 0
A
Trigonal Bipyramidal
8
Q
E 5 LP 1
A
See Saw
9
Q
E 5 LP 2
A
T Shape
10
Q
E 5 LP 3
A
Linear
11
Q
E 6 LP 0
A
Octahedral
12
Q
E 6 LP 1
A
Square Pyramidal
13
Q
E 6 LP 2
A
Square Planar
14
Q
Linear Charge
A
Non Polar
15
Q
Trigonal Planar Charge
A
Non Polar
16
Q
Bent Charge
A
Polar
17
Q
Tetrahedral Charge
A
Non Polar
18
Q
Trigonal Pyramid Charge
A
Polar
19
Q
Trigonal Bipyramidal Charge
A
Non Polar
20
Q
See Saw Charge
A
Polar
21
Q
T Shape Charge
A
Polar
22
Q
Octahedral Charge
A
Non Polar
23
Q
Square Pyramid Charge
A
Polar
24
Q
Square Planar Charge
A
Non Polar
25
If a molecule is polar it has what forces?
Dipole Dipole
26
Higher Temperatures do what to vaporization pressure
Increase
27
Higher Surface Areas do what to vaporization pressure?
Increase
28
Container Size does what to vaporization pressure?
Increase
29
Weaker Intermelecular forces do what to vaporation pressure
Higher Vaporization pressure.
Water has Hydrogen bonding and will vaporize slower than compounds with weaker intermolecular forces
30
Equation to get Molarity (M)
amount of solute (In mol) / volume of solution (In L)
31
Equation to get Molality (m)
Amount of solute (in mol) / mass of solvent (In kg)
32
Equation of mole fraction (x)
amount of solute (in mol) / total amount of solute and solvent (in mol)
33
Equation for Mole Percent (mol %)
amount of solute (in mol) / total amount of solute and solvent (in mol) x100%
34
Equation of parts by volume (%, ppm, ppb)
volume solute / volume solution x multiplication factor
35
What is c?
Specific Heat
36
How much heat in kJ is required to convert 55.0
g benzene at –15.5 ˚C to benzene at 42.4 ˚C?
How do you do this problem.
You find the molar mass of the compound.
Find how many rate changes there are.
q=mcat for the first phase (IN J)
mass->molar mass->enthalpy (given) (IN KJ)
q=mcat for last phase (IN J)
Convert to KJ
Add together
37
At 20°C, an aqueous solution that is 20.0% ammonium chloride by mass has a density of What is the
molarity of ammonium chloride in the solution? The formula weight of Cl is
How do you solve this problem.
Its asking for the molarity so you use the molarity formula which is amount of solution (in mol) / volume of solution (in L)
you start by assuming 100g of solution. convert 100g->given g/ml->1000mL in a L
this calculation gives you the L
Then you take the assumed amount of solute (20g) and convert it with the mol value you were given.
plug in with the molarity formula
38
At 20°C, a 1.33 M aqueous solution of ammonium chloride has a density of What is the molality of
ammonium chloride in the solution? The formula weight of NH4Cl is
How do you solve this problem?
You are wanting to find the molality which is amount of solute (in mol) / mass of solvent (in kg)
you are given the Moles of the solution and need to assume 1L
1L-1000mL->given amount for mL
then you take the Moles you were given
1.33->amount given for mol
then divide these numbers amount of solute (in mol) / mass of solvent (in kg)
39
Is the solute or solvent usually in a lower amount?
Solute
40
At 20°C, a 0.756 M aqueous solution of ammonium chloride has a density of What is the mass % of
ammonium chloride in the solution? The formula weight of NH4Cl is
How do you solve this problem?
It is asking for the mass percent which is amount of solute (in g) / total amount of solution (in g)
you can assume 1 L->1000mL->given amount of mL
then you take the moles given
0.756->given amount of mols in g
solute/total x 100
41
what is the equation for vapor pressure
Psoln = (xSolvent)(PSolvent)
42
what does P mean?
Vapor Pressure
43
A solution is prepared by adding 20.00 g of lactose (milk sugar) to 110.0 g of water at The partial pressure of
water above the solution is ________ torr. The vapor pressure of pure water at 55°C is 118.0 torr. The molar mass of
lactose is
How do you solve this problem.
Whenever you see vapor pressure you need to use the equation
psoln = (xSolvent)(PSolvent)
the PSolvent will most likely be given
Using what you are given which in this case is the mass in grams of the substances, convert both to moles
take the moles of solvent / total moles
take that number and multiply it by the vapor pressure of the solvent
the solvent is the higher amount
44
A solution is prepared by dissolving 5.00 g of glycerin ( ) in 201 g of ethanol The freezing point of
the solution is ________°C. The freezing point of pure ethanol is at 1 atm. The molal-freezing-point-depression
constant ( ) for ethanol is The molar masses of glycerin and of ethanol are 92.1 g/mol and 46.1 g/mol,
respectively
How do you solve this problem?
When you see the freezing point, you use the equation
DeltaTf = (m)(kf)
to get the molality you use the equation
moles of solute / kg of solvent
take the given grams of the solute and convert to moles
convert the given grams of solvent to kg
divide
multiply by the given kf
take the freezing point and subtract the value you calculated
45
What is the expected freezing point of a 0.50 m solution of Na2SO4 in water? Kf for water is 1.86°C/m.
how do you solve this?
It might look like you have all of the information to do the simple problem but you have to factor in the van hoff factor (i)
mutiply everything by 3
46
The reaction is first order and has a rate constant of 4.82 × at 64°C. If the reaction is initiated with 0.092 mol in a
1.00-L vessel, how many moles remain after 151 s
How do you solve this?
If you see "Initiated" you are using the equation
ln[A]t = -kt+ln[A]0
plug in all the numbers and then take that number and remember do
e^the calculated number
47
What is k?
Rate Constant
48
For a particular first-order reaction, it takes 6.0 minutes for the concentration of the reactant to decrease to 25% of its
initial value. What is the value for rate constant (in s-1) for the reaction?
How do you solve this?
Take the equation
ln[A]t = -kt + ln[A]0
plug in all the known numbers and solve algebraically
remember % are decimals and the time needs to be in seconds
49
For the first-order reaction, 2 N2O(g) → 2 N2(g) + O2(g), what is the concentration of N2O after 3 half-lives if mol
of N2O is initially placed into a 1.00-L reaction vessel?
How do you solve this?
Literally just divide the given moles by 2 three times
This is because a half life is divided by 2