Chemistry Flashcards

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1
Q

what is a bronsted acid and a bronsted base?

A

A bronsted lowry acid donates protons

A Bronsted base accepts protons

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2
Q

what is a lewis acid and lewis base

A

They both transfer electrons to form a bond,

the base is the electron donor

the acid is the electron donor

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3
Q

what are salt bridges?

A
  • contain inert electrolytes
  • in a galv cell, only a wire were provided for this electron flow, the reaction would stop, because excess pos and excess neg on both sides would accumulate. causing no oxi-red reaction to take place,so the current would cease
  • so we use salty bridges, to permit the exchange of cations and anions,
    it contains KCl or NH4NO3 which are inert electrolytes,
  • they contain ions that will not react with the electrodes or the ions in the solution
  • anions diffuse to the anode side, to balance the charge of newly created cations
  • the cations of the salt bridge, go to the cation side of the bridge, to balance the cathode side, to balance the anions that left
  • when cations are reduced, they precipate onto the electrode
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4
Q

Describe Nucleophiles

A
  • Nuclease loving, they have lone pairs or pi bonds that form new bonds to electrophiles.
  • determined by 4 factors
  • charge- nucleophilicty increases with electron density (more neg charge)
  • electronegativity- nucleophilicty decreases as electroneg increases,
  • steric hinderance- bulkier molecules are less nucelophilic
  • solvent- protic solvesn can inhibit nucelophilicity by protoniating the nucleophile or hydrogen bonding
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5
Q

what is conduction and convection?

A
  • conduction occrus when heat is transferred by direct collsion between molecuels in one material and molecules in another
  • convection- when molecules of a liquid or gas are heated, then moved from once place to another
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6
Q

what are diastereomers?

A
  • isomers that have different chiral configurations at one or more chiral centers
  • they can be distinguished by IR spectroscopy
  • example would be cis/trans isomers
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7
Q

what happens to boiling point as hydrogen bonding decreases

A

It decreases

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