Chemistry Flashcards
1
Q
what is a bronsted acid and a bronsted base?
A
A bronsted lowry acid donates protons
A Bronsted base accepts protons
2
Q
what is a lewis acid and lewis base
A
They both transfer electrons to form a bond,
the base is the electron donor
the acid is the electron donor
3
Q
what are salt bridges?
A
- contain inert electrolytes
- in a galv cell, only a wire were provided for this electron flow, the reaction would stop, because excess pos and excess neg on both sides would accumulate. causing no oxi-red reaction to take place,so the current would cease
- so we use salty bridges, to permit the exchange of cations and anions,
it contains KCl or NH4NO3 which are inert electrolytes, - they contain ions that will not react with the electrodes or the ions in the solution
- anions diffuse to the anode side, to balance the charge of newly created cations
- the cations of the salt bridge, go to the cation side of the bridge, to balance the cathode side, to balance the anions that left
- when cations are reduced, they precipate onto the electrode
4
Q
Describe Nucleophiles
A
- Nuclease loving, they have lone pairs or pi bonds that form new bonds to electrophiles.
- determined by 4 factors
- charge- nucleophilicty increases with electron density (more neg charge)
- electronegativity- nucleophilicty decreases as electroneg increases,
- steric hinderance- bulkier molecules are less nucelophilic
- solvent- protic solvesn can inhibit nucelophilicity by protoniating the nucleophile or hydrogen bonding
5
Q
what is conduction and convection?
A
- conduction occrus when heat is transferred by direct collsion between molecuels in one material and molecules in another
- convection- when molecules of a liquid or gas are heated, then moved from once place to another
6
Q
what are diastereomers?
A
- isomers that have different chiral configurations at one or more chiral centers
- they can be distinguished by IR spectroscopy
- example would be cis/trans isomers
7
Q
what happens to boiling point as hydrogen bonding decreases
A
It decreases