Chemical Reactions- Reversible reactions Flashcards

1
Q

What can happen in reversible reaction?

A

The product molecules can themselves react with each other or decompose and form reactant molecules again. It can occur in both directions

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2
Q

Give an example of a hydrated salt- chemical

A

CuSO4.5H20

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3
Q

What are anhydrous salts?

A

Those that have lost their eater of crystallization by heating

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4
Q

Give the chemical equation for the dehydration of copper (II) Sulphate

A

CuSO4.5H2O (reversible reaction sign) CuSO4 + 5H20

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5
Q

What is the colour change for the dehydration of copper II sulphate

A

Blue to white

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6
Q

What happens when anhydrous copper sulphate crystals are added to water?

A

They turn blue and heat is given off

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7
Q

What happens when hydrous copper sulphate is heated?

A

Blue crystals turn white and a clear colourless liquid collects at the top

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8
Q

Give the equation for the dehydration of cobalt(II) Chloride

A

CoCl2. 6H2O (reversible reaction sign) CoCl2 + 6H2O

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9
Q

When is equilibrium reached?

A

When the rate of forward reaction = rate of reverse reaction

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10
Q

What are characteristics of a reaction at equilibrium?

A
  1. It is dynamic- molecules on the left and on the right of the equation are changing into each other
  2. the concentration of reactant and products are constant
  3. Occurs in a closed system so that none of the participating chemical species are able to leave the reaction
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11
Q

In the reaction between H2 and N2 in Haber process, What is happening at the beginning?

A

When only H2 and N2 are present at the beginning of the reaction the forward reaction is at its highest since conc of H2 and N2 are at their highest

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12
Q

In the reaction between H2 and N2 in Haber process, what happens after the beginning?

A

Conc of H2 and N2 decrease so the rate of forward reaction decreases and at the same time the conc of ammonia is increasing so the backward reaction increases

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13
Q

In the reaction between H2 and N2 in Haber process, what happens in the end?

A

Since no gases escape, equilibrium is reached

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14
Q

Give the equation for the Haber process

A

3H2 + N2 (reversible reaction sign) 2NH3

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15
Q

What happens when the equilibrium position shifts to the left?

A

The concentration of reactants increase

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16
Q

What happens when the equilibrium position shifts to the right?

A

The concentration of product increases

17
Q

What does the presence of a catalyst do? Why?

A

Does not affect the position of equilibrium but increases the rate at which equilibrium is reached. This is because the rate of both forward and backward reactions increase

18
Q

What is Le Chatelier’s Principle?

A

When a change is made to the conditions of a system at equilibrium the system automatically moves to oppose the change

19
Q

What happens when there is an increase in temperature?

A

Equilibrium moves in the endothermic direction to reverse the change

20
Q

What happens when there is a decrease in temperature?

A

Equilibrium moves in the exothermic direction to reverse the change

21
Q

What happens when there is an increase in pressure?

A

Equilibrium shifts in the direction that produces the smaller number of molecules of gas to decrease the pressure

22
Q

What happens when there is a decrease in pressure?

A

Equilibrium shift in the direction that produces the larger number of molecules of gas to increase the pressure

23
Q

What happens when there is an increase in concentration?

A

Equilibrium shifts to the RIGHT to reduce the effect of increase in concentration of reactant

24
Q

What happens when there is a decrease in concentration?

A

Equilibrium shifts to the LEFT to reduce the effect of decrease in reactant