Chemical Kinetics (Module 9) Flashcards
The study of the rate of chemical change and the way this is influenced by conditions of concentration of the reactants, products, and chemical species that may be present, and by factors such as solvent, pressure, and temperature.
reaction kinetics
study of the rate of a chemical reaction
chemical kinetics
The speed with which the reaction occurs
reaction / degradation rate
importance of knowledge in chemical kinetics
- Maintaining proper storage conditions of drug products
- Providing beyond use date of prescriptions
- Preparation and storage of sterile products
- Ensuring the patient receives the correct dose
- The length of time a drug remains stable
Identifying expiration dating or determination of shelf-life
(effect of temperature on reaction rate) rate of chemical reaction generally ____ on increasing the temperature
increases
(nature of reactants) reactions involving _________ including the proton transfer reactions are usually ______.
polar and ionic substances, very fast
(nature of reactants) on the other hand, the reaction in which bonds are _____, or electrons transferred is _____
rearranged, slow
(nature of reactants) are slow compared to the ionic substance
oxidation-reduction reactions
(nature of reactants) are relatively much slower
substitution reactions
(pH of the medium) the rate of a reaction taking place in aqueous solution often depends upon the ____________. Some reactions become fast on increasing the H+ ion concentration while some become slow.
ion concentration
(concentration of reactants) he rate of a chemical reaction is _______ to the concentration of the reactants means the rate of reaction decreases with a decrease in concentration.
directly proportional
(surface area of the reactant) the larger the surface are, the probability of collisions _____ and thus rate of reaction ______
increases
(presence of catalyst) the greater the decrease in the activation energy caused by the catalyst, the higher will be the reaction rate. In the presence of a catalyst, the reaction follows a path of lower activation energy.
increase
(effect of sunlight) there are many chemical reactions whose rate is influenced by radiations particularly by ultraviolet and visible light. Such reactions are called
photochemical reactions