Chemical kinetics Flashcards

1
Q

Reaction rate

A

change in concentration/ time

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2
Q

The _____ the concentration, the ____ collision therefore a ______ rate

A

higher/ lower
more/ less
faster/ slower

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3
Q

Instantaneous rate

A

Rate at a specific moment in time

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4
Q

Rate law

A

rate = rate constant (k) * reactants [A][B]

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5
Q

Reaction order is defined in terms of _______ concentration, not the __________

A

reactant

product

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6
Q

Integrated rate law

A

Shows the concentration at any given time

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7
Q

Zeroth order

A

slope = -k

| + 
|    +
|       +
|           +
\_\_\_\_\_\_\_\_\_
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8
Q

First order equation

A

ln[A] t = -kt + ln[A]o

|  +
|    +
|       +
|            +
\_\_\_\_\_\_\_\_\_
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9
Q

Second order equation

A
1/[A]t= kt + 1/[A]o
slope = k
|         +
|       +
|    +
| +
\_\_\_\_\_\_\_\_\_
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10
Q

Factors affecting rate pf collision

A

frequency , temperature , concentration

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11
Q

Effective collsion

A

Results in reactions

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12
Q

Activation energy

A

Required to initiate reactions

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13
Q

Transition state

A

Temporary species formed as molecules collide

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14
Q

Lower the activation energy _____ the reaction

A

faster

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15
Q

Arrhenius equation

A

ln (k1/ k2) = -(E/R) * change in temperature

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16
Q

Unimolecular

A

1 reactant

17
Q

Bimolecular

A

2 reactants

18
Q

Termolecular

A

3 reactants

19
Q

Rate determining step

A

The slowest reaction rate in the sequence of steps

20
Q

Catalysts

A

Increases the rate of a chemical reaction by lowering the activation energy causes more effective collisions between molecules