Chemical Equilibrium Flashcards
Law of mass action/Keq
Keq is the ratio of products to reactants at equilibrium (when the rates of the forward and reverse reactions are equal)
aA + bB = cC + dD
Keq = (C^c)(D^d)/(A^a)(B^b)
dependant on temp
larger Keq = rxn forms more product than reactant
Keq for reverse reaction: 1/Keq
dynamic equilibrium
point at which the forward and reverse reaction rates are equal
reaction quiotient
concentrations are not constant.
f Q
reaction has not reached the equilibrium point.
deltaG is negative.
concentration of reactants is greater than the concentration of products.
If Q=Keq, what is happening with the reaction?
reaction has reached equilibrium
deltaG is zero
concentrations of reactants and products are at equilibrium proportions