Chemical Equilibrium Flashcards

1
Q

When is a

Chemical reaction in equilibirum

A

When the compostion of reactants remains constant indefinitely

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2
Q

WHat does

Value of equilibrium constant K indicate

A

Position of equilibirum

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3
Q

Value of pure solids and liquids in equilibria

A

1

They are seen as constant

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4
Q

Equilibirum constant K is dependent on

A

Reaction temperature ONLY.
It is independent of Concentration and pressure

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5
Q

K in

Endothermic & Exothermic reactions

A

Temperature increase in endothermic reacrion increases K and yield of product.
Temperature increase in **exothermic **decreases K and yield of product

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6
Q

Does a

Catalyst affect K

A

NO!

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7
Q

Ionisation of water

A

2H2O(l)>H3O+(aq) +OH-(aq)

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8
Q

Amphoteric

A

Can act as an acid and a base

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9
Q

Dissosciation Constant for ionisation of water

A

Kw
Kw=[H3O+][OH-]

Known as the ionic product

IT VARIES WITH TEMPERATURE !!

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10
Q

Kw at 25 degrees celcius

A

1 x 10-14

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11
Q

What are [H3O+] and [OH-] in water and aqueous solutions with a pH of 7

A

Both are 10-7 mol l-1 at 25 degrees

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12
Q

The bronsted lowry definition of acids and bases

A

An acid is a proton donor and a base is a proton acceptor

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13
Q

For every ..

A

Acid there is a conjugate base, formed by the loss of a proton
Base there is a conjugate acid, formed by the gain of a proton

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14
Q

Strong acids and bases

And examples

A

Completely dissociate into ions in aqueous solutions

Hydrochloric acid, sulpuric acid, nitiric acid

Metal hydroxides

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15
Q

Weak acids and bases

And examples

A

Only partially dissociate into ions in aqueous solutions

Ethanoic acid, carbonic, sulfouros acid

Ammonia and amines

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16
Q
A