Chemical Equilibrium Flashcards
When is a
Chemical reaction in equilibirum
When the compostion of reactants remains constant indefinitely
WHat does
Value of equilibrium constant K indicate
Position of equilibirum
Value of pure solids and liquids in equilibria
1
They are seen as constant
Equilibirum constant K is dependent on
Reaction temperature ONLY.
It is independent of Concentration and pressure
K in
Endothermic & Exothermic reactions
Temperature increase in endothermic reacrion increases K and yield of product.
Temperature increase in **exothermic **decreases K and yield of product
Does a
Catalyst affect K
NO!
Ionisation of water
2H2O(l)>H3O+(aq) +OH-(aq)
Amphoteric
Can act as an acid and a base
Dissosciation Constant for ionisation of water
Kw
Kw=[H3O+][OH-]
Known as the ionic product
IT VARIES WITH TEMPERATURE !!
Kw at 25 degrees celcius
1 x 10-14
What are [H3O+] and [OH-] in water and aqueous solutions with a pH of 7
Both are 10-7 mol l-1 at 25 degrees
The bronsted lowry definition of acids and bases
An acid is a proton donor and a base is a proton acceptor
For every ..
Acid there is a conjugate base, formed by the loss of a proton
Base there is a conjugate acid, formed by the gain of a proton
Strong acids and bases
And examples
Completely dissociate into ions in aqueous solutions
Hydrochloric acid, sulpuric acid, nitiric acid
Metal hydroxides
Weak acids and bases
And examples
Only partially dissociate into ions in aqueous solutions
Ethanoic acid, carbonic, sulfouros acid
Ammonia and amines