Chemical Equilibria Flashcards

1
Q

What can cause imbalances in a chemical reaction?

A
  1. Temperature.
  2. Pressure.
  3. Energy.
  4. Concentration.
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2
Q

Systems at equilibrium are ________ and ________.

A

dynamic, reversible

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3
Q

What two states of matter CANNOT be used in equilibrium equations and why?

A
  1. Solids and liquids.
  2. Pure substances do not change concentration.
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4
Q

What is Kforward?

A

Products over reactants.

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5
Q

What is Kreverse?

A

Reactants over products.

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6
Q

What is Kc dependent on?

A

Temperature.

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7
Q

What are the units of K?

A

K is unitless.

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8
Q

If Kc > 1, what is the equation said to be?

A

Product favored because there will be more product molecule than reactant molecules.

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9
Q

If Kc<1, what is the equation said to be?

A

Reactant favored because there will be more reactant molecules than product molecules.

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10
Q

What is the conversion of Kp to Kc?

A

Kp= Kc x (RT)^mols. prod. - mols. reac.

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11
Q

When is Kp=Kc?

A

When delta n is zero.

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12
Q

Q=K.

A

Equilibrium.

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13
Q

Q<K.

A

The system shifts to the products.

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14
Q

Q>K.

A

The system shifts to the reactants.

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15
Q

If reactants increase, which way does the reaction shift?

A

To the products.

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16
Q

If reactants decrease, which way does the reaction shift?

A

To the reactants.

17
Q

If products increase, which way does the reaction shift?

A

To the reactants.

18
Q

If products decrease, which way does the reaction shift?

A

To the products.

19
Q

As pressure increases or volume decreases, which side is shifted towards?

A

The side with fewer gas moles or towards the reactants.

20
Q

As pressure decreases or volume increases, which side is shifted towards?

A

The side with more gas moles or towards the products.

21
Q

If the moles of gases are equal, which side is shifted towards?

A

Neither, no shift occurs.

22
Q

When the reaction is exothermic, where is heat placed?

A

On the products side.

23
Q

When the reaction is endothermic, where is heat placed?

A

On the reactants side.

24
Q

Do catalysts affect the equilibrium position of a system?

A

No.